To lock atmospheric
CO2 at anthropogenic timescale,
fast weathering silicates can be applied to soil to speed up natural
CO2 sequestration via enhanced weathering. Agricultural
lands offer large area for silicate application, but expected weathering
rates as a function of soil and crop type, and potential impacts on
the crops, are not well known. This study investigated the role of
plants on enhanced weathering of wollastonite (CaSiO3)
in soils. Using rooftop pot experiments with leguminous beans (Phaseolus vulgaris L.) and nonleguminous corn (Zea mays L.), CO2 sequestration was inferred
from total inorganic carbon (TIC) accumulation in the soil and thermogravimetric
analysis, and mineral weathering rate was inferred from alkalinity
of soil porewater. Soil amendment with wollastonite promoted enhanced
plant growth: beans showed a 177% greater dry biomass weight and corn
showed a 59% greater plant height and a 90% greater dry biomass weight.
Wollastonite-amended soil cultivated with beans showed a higher TIC
accumulation of 0.606 ± 0.086%, as compared to that with corn
(0.124 ± 0.053%). This demonstrates that using wollastonite as
a soil amendment, along with legume cultivation, not only buffers
the soil against acidification (due to microbial nitrogen fixation)
but also sequesters carbon dioxide (12.04 kg of CO2/tonne
soil/month, 9 times higher than the soil without wollastonite amendment).
This study details a comprehensive analysis of apple and grape pomaces that were generated in the course of juice and wine production, respectively. An extensive physicochemical analysis of these pomaces was performed to determine the elemental composition, ash content, sugar profile, and lignocellulose content. Scanning electron microscopy (SEM) images were taken to examine the morphology of the pomaces. Thermal stability was also examined using thermogravimetric analysis (TGA). Infrared spectroscopy was performed to observe the functional groups on the surfaces of the pomace samples. Grape pomace (GP) had better thermal stability than apple pomace (AP), but washing AP improved its thermal stability. The results from this study provide crucial information for various value-added applications of both apple and grape pomaces, especially for applications which are temperature-dependent. The diversion of these materials from waste back into the economic stream can alleviate their environmental burden and promote sustainable product development.
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