The polymer cement mortar (PCM) overlay method is a promising solution for strengthening deteriorated concrete structures in which the occurrence of premature debonding at the interfaces prevents the strengthened structures from achieving full serviceability. The purpose of this study is to improve the concrete–PCM interfacial bond to prevent premature debonding. There are two main focuses of this study: (i) investigation of the effectiveness of adding 5% silica fume to PCM in forming a chemical connection between concrete and PCM, based on a direct single-surface shear test using two roughness levels of concrete (smooth and rough) and microstructure analysis and (ii) performance evaluation of the bond between substrate concrete and a PCM overlay with/without silica fume at early ages and with different moisture conditions at the interface, based on a bi-surface shear test using rough substrate concrete surface. The inclusion of 5% silica fume with PCM caused an improvement in the interfacial strength (approximately 113% relative to the normal PCM in cases of without primer), with a smooth concrete substrate surface where mechanical bonding had less influence. In addition, lower Ca/Si values in the interface of modified 5% silica PCM specimens compared to the normal PCM specimens quantified by energy-dispersive X-ray spectroscopy (EDS) indicate the formation of a chemical connection at the concrete–PCM interface by transforming harmful Ca(OH)2 into more C-S-H which strongly improves the bonding strength. As a repair layer mortar, the positive influence of silica fume in modified 5% silica PCM specimens was also found at early ages and with different moisture conditions at the interface compared to the normal PCM. In conclusion, the addition of silica fume to the PCM caused chemical connection at the concrete–PCM interface and improved the interfacial performance.
The long-term performance of the concrete–polymer cement mortar (PCM) interface under environmental exposure is crucial to the safety of the PCM overlaying method as the environmental exposure of the repaired structures caused further degradation of the interface, leading to a significant reduction in intended service life. This study investigates the durability enhancement effect of silica fume of the concrete–PCM interface, considering an individual action of elevated temperature (e.g., 60 °C) [constant (short and moderate duration) and cyclic conditions] and moisture content [continuous immersion and wetting/drying (W/D) cycle]. Our previous research confirmed that the use of silica fume forms more C-S-H with strong binding force and enhances the interfacial bonding strength due to the denser microstructure at the interface, and it is expected to be utilized for durability purposes under the aforementioned exposure conditions. Under all elevated temperature exposure conditions, the reduction percentage of the interfacial performance corresponding to the respective reference specimens reduced significantly with the inclusion of silica fume with overlay material. The occurrence of interface fracture at lower load and a greater number of pure interface fracture modes observed in normal PCM specimens compared to modified PCM specimens indicates a positive influence of higher adhesion with better durability of modified PCM overlay with substrate concrete. Under both conditions of moisture content, significant reduction in interfacial strength was observed in normal PCM specimens. In all cases, the reducing ratio of interfacial strength was higher in normal PCM compared to modified PCM, indicating a positive influence of silica fume under moisture content. Furthermore, silica fume inclusion shifts the fracture mode from pure interfacial fracture to composite fracture mode, indicating a positive response of silica fume to improve the resistance of interface fracture under moisture content. Conclusively, the use of silica fume improves concrete–overlay layer adhesion and enhances the bonding durability under environmental exposure.
Currently, concrete structures are at risk of deteriorating conditions due to their exposure to various severe environments. Repairing and strengthening these structures is a better solution than replacing them by new constructions. As a retrofitting method, the top/bottom surface overlaying or jacketing method is commonly used around the world. In this method, polymer cement mortar (PCM) is sprayed/troweled onto the surfaces of concrete, and PCM adhesive strengthens the concrete structures. However, the concrete-PCM interface is considered to be the weakest part of a structure, and it may cause brittle fracture. This study focused on how this interface can be strengthened more effectively to prevent brittle fractures and investigated the effects of applying surface penetrant and silica fume from the perspective of chemical reactions. In addition, the reaction time relationship between PCM hydration and surface penetrant application time is also investigated based on a preliminary experiment. Mixing silica fume into PCM was conclusively found to strengthen the interface bonding strength in some conditions. Applying surface penetrant to an interface could decrease the interface strength if the application time was inappropriate. However, the results of an application time experiment indicated that it is possible to strengthen the interface via the surface penetrant.
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