A Fe3O4/SiO2/PATL/MnO2 core/shell nanocomposite was synthesized via an ultrasound-assisted method and its catalytic activity for the aerobic oxidation of alcohols to aldehydes and ketones was evaluated .
A new magnetically recoverable nanocatalyst was prepared by functionalization of mesoporous silica (SBA-15) with a Schiff base ligand, and then immobilization of palladium nanoparticles on it using a simple procedure. This heterogeneous catalyst was fully characterized using appropriate analyses and its catalytic efficiency was investigated in Heck reaction using iodo-, bromo-and chlorobenzene derivatives and styrene, with the aim of synthesizing stilbene derivatives, a class of compounds with a variety of pharmacological properties. Some of the characteristics of this nanocatalyst include good dispersion of palladium nanoparticles on the SBA-15 support, easy separation, catalyses the production of stilbene derivatives in a short time with excellent yields even for bromo-and chlorobenzene, and preservation of its catalytic activity after eight reaction cycles.
Correction for ‘Novel approach to synthesizing polymer-functionalized Fe3O4/SiO2–NH2via an ultrasound-assisted method for catalytic selective oxidation of alcohols to aldehydes and ketones in a DMSO/water mixture’ by Mahsa Dehghan et al., RSC Adv., 2015, 5, 92335–92343.
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