Dilute magnetic semiconductors and wide gap oxide semiconductors are appealing materials for magnetooptical devices. From a combinatorial screening approach looking at the solid solubility of transition metals in titanium dioxides and of their magnetic properties, we report on the observation of transparent ferromagnetism in cobalt-doped anatase thin films with theconcentration of cobalt between 0 and 8%. Magnetic microscopy images reveal a magnetic domain structure in the films, indicating the existence of ferromagnetic long-range ordering. The materials remain ferromagnetic above room temperature with a magnetic moment of 0.32 Bohr magnetons per cobalt atom. The film is conductive and exhibits a positive magnetoresistance of 60% at 2 kelvin.

The oxygen evolution reaction that occurs during water oxidation is of considerable importance as an essential energy conversion reaction for rechargeable metal–air batteries and direct solar water splitting. Cost-efficient ABO3 perovskites have been studied extensively because of their high activity for the oxygen evolution reaction; however, they lack stability, and an effective solution to this problem has not yet been demonstrated. Here we report that the Fe4+-based quadruple perovskite CaCu3Fe4O12 has high activity, which is comparable to or exceeding those of state-of-the-art catalysts such as Ba0.5Sr0.5Co0.8Fe0.2O3−δ and the gold standard RuO2. The covalent bonding network incorporating multiple Cu2+ and Fe4+ transition metal ions significantly enhances the structural stability of CaCu3Fe4O12, which is key to achieving highly active long-life catalysts.

Combinatorial laser molecular-beam epitaxy method was employed to fabricate epitaxial ZnO thin films doped with all the 3d transition metal (TM) ions in a high throughput fashion. The solubility behavior of TM ions was discussed from the viewpoints of the ionic radius and valence state. The magneto-optical responses coincident with absorption spectra were observed for Mn- and Co-doped samples. Cathodoluminescence spectra were studied for Cr-, Mn-, Fe-, and Co-doped samples, among which Cr-doped ZnO showed two sharp peaks at 2.97 eV and 3.71 eV, respectively, at the expense of the exciton emission peak of pure ZnO at 3.25 eV. Different magnetoresistance behavior was observed for the samples codoped with n-type carriers. Ferromagnetism was not observed for Cr- to Cu-doped samples down to 3 K.

S U M M A R YTsunami waves propagating across long distances in the open-ocean can induce atmospheric gravity waves by dynamic coupling at the surface. In the period range 10 to 20 minutes, both have very similar horizontal velocities, while the gravity wave propagates obliquely upward with a vertical velocity of the order of 50 m s −1 , and reaches the ionosphere after a few hours. We use ionospheric sounding technique from Global Positioning System to image a perturbation possibly associated with a tsunami-gravity wave. The tsunami was produced after the M w = 8.2 earthquake in Peru on 2001 June 23, and it reached the coast of Japan some 22 hours later. We used data from the GEONET network in Japan to image small-scale perturbations of the Total Electron Content above Japan and up to 400 km off shore. We observed a short-scale ionospheric perturbation that presents the expected characteristics of a coupled tsunami-gravity wave. This first detection of the gravity wave induced by a tsunami opens new opportunities for the application of ionospheric imaging to offshore detection of tsunamis.

Analysis of global positioning system data shows that the rate of crustal deformations in the Tokai region of Japan, a seismic gap area, changed over the past 18 months. Kalman filtering analysis shows aseismic slip on the plate boundary in the western Tokai region centered on Lake Hamana, adjacent to the anticipated Tokai earthquake source area. The cumulative moment magnitude reaches 6.7 in June 2002 with a relative slip increase northeast of Lake Haman from January 2002. An existence of aseismic slip in the western Tokai supports the hypothesis of a silent event as the cause of uplifting several days before the 1944 Tonankai earthquake.