The use of hydrodynamic cavitation (HC) as a wastewater treatment and anaerobic digestion pretreatment is a well-known process. However, most of the experiments have been done at laboratory scale and using a low concentration of total solids in the sludge treated. In this study, the waste-activated sludge has been mixed with pig slurry with the aim of treating two wastes rich in nutrients and organic matter. The HC has been studied not only at laboratory scale but also at industrial scale (up to 500 L), using a novel rotating device consisting of a rotor with multiple teeth that rotate inside a grooved stator. The effectiveness of the process has been calculated using the disintegration degree (DD) and analyzing the volatile fatty acids, while the energy efficiency has been determined with specific energy of the sludge solubilization (SE SCOD) and the specific energy. Results show that both the SE SCOD and the specific energy decrease when the cavitation process is scaled from laboratory scale to industrial scale. Specifically, SE SCOD decreases from 2.71 × 10 2 to 0.16 × 10 2 kJ/g SCOD and specific energy decreases from 3.58 × 10 4 to 2.85 × 10 3 kJ/kg TS while DD values show reasonable values up to 17%. © 2020 Water Environment Federation • Practitioner points • A new industrial hydrodynamic cavitation device has been developed to treat industrial wastewater without chemical additives • A volume up to 500 L has been treated at industrial scale experiments. • Sludge with 7% of total solids content was satisfactorily disintegrated. • The process scale-up lead to an energy efficiency enhancement.
The present paper addresses the development and use of a new potentiometric electronic tongue for both qualitative and quantitative characterization of natural mineral waters. The electronic tongue is particularly related to the conductivity and ion content of/in the water sample. The analytical system is based on six ion-selective electrodes whose membranes are formulated to provide either cationic or anionic response and considering plasticizers with different dielectric constants (bis(2-ethylhexyl) sebacate, 2-nitrophenyl octyl ether or tricresylphosphate), while keeping the polymeric matrix, i.e., poly(vinyl chloride). Notably, the absence of any ionophore in the membrane provides a general response profile, i.e., no selectivity toward any special ion, which is convenient for the realization of an effective electronic tongue. The dynamic response of the tongue toward water samples of different chemical compositions and geographical locations has been obtained. At the optimized experimental conditions, the tongue presents acceptable repeatability and reproducibility (absence of hysteresis). The principal component analysis of the final potential values observed with the six electrodes allows for the differentiation and classification of the samples according to their conductivity, which is somehow related to the mineralization. Moreover, quantitative determination of the six main ions in the water samples (i.e., chloride, nitrate, hydrogen carbonate, sulfate, sodium, calcium, and magnesium) is possible by means of a simple linear calibration (and cross-validation) model.
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