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Superhydrophobic surfaces have received increasing attention due to their excellent water repellency, but the fragile stability of superhydrophobic coatings has been a huge hindrance to their applications. In this work, we constructed a layer of mullite fibers on the surface of a ceramic substrate using high-temperature molten salt. Then, we obtained a superhydrophobic surface with a contact angle greater than 150° via soaking the sample with an alcoholic sol containing modified particles. On the one hand, this interlaced three-dimensional fiber structure increases the surface area and roughness, providing more locations for attaching superhydrophobic particles, as well as improving the water repellency. On the other hand, this fiber layer has a height difference, which protects the superhydrophobic particles attached at lower positions, and when an external object contacts the surface, it gives priority to the stable mullite fibers, reducing the direct contact between superhydrophobic particles and external objects and improving the stability of the superhydrophobic coating. After abrasion with sandpaper, the sample with the mullite fiber layer showed excellent stability compared to the samples without the fiber layer, indicating the significant protective effect of the fiber layer. This paper provides a potential method to enhance the stability of superhydrophobic ceramic surfaces.

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