No abstract

Nonlinear spectroscopic method based on degenerate four-wave mixing allows unusually sensitive measurement of isotopes and hyperfine profiles with sub-Doppler spectral resolution. Compared to other isotope capable methods including mass spectrometry, wave mixing offers a simple, more cost effective approach with minimal sample preparation steps. Since no two hyperfine profiles are alike, hyperfine-based isotope analysis offers unambiguous isotope information. Unlike mass-based methods such as mass spectrometry, frequency-based wave-mixing spectroscopy offers more information rich spectra. A non-planar 3-D wave-mixing optical setup generates a coherent signal beam in its own space and propagation direction. Hence, virtually 100% of the signal can be collected and detected conveniently. Using compact solid-state lasers and popular atomizers, a wave-mixing setup is relatively compact. Sub-Doppler spectral resolution can be further enhanced by using simple low-pressure atomizers. Ultrasensitive fingerprinting of important isotopes promises many potential applications.