The analysis of phenomena related to gas transport in hard coal is important with regard to the energetic use of coal bed methane (CBM), the reduction of greenhouse gas emissions to the atmosphere (CO2) and the prevention of natural hazards such as methane hazards and gas and rock outbursts. This article presents issues concerning the feasibility and scope of applying the unipore and bidisperse diffusion models to obtain knowledge concerning the kinetics of methane sorption and its diffusion in the carbon structure, depending on its petrography. Laboratory tests were carried out on coal samples which varied in terms of petrography. Quantitative point analyses were carried out, based on which content of groups of macerals was determined. The degree of coalification of coal samples was also determined based on measurements of vitrinite reflectivity R0 and the volatile matter content Vdaf. Sorption kinetics were also investigated, and attempts were made to adjust the unipore and bidisperse models to the real sorption kinetic courses. This allowed the identification of appropriate coefficients controlling the course of sorption in mathematical models. An attempt was also made to assess the possibility of applying a given model to properly describe the phenomenon of methane sorption on hard coal.

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The content of natural methane in hard coal seams, called methane-bearing capacity, is the basic parameter that enables the level of methane hazard to be determined in hard coal mines. This parameter is also used to determine the potential quantities of methane that can be collected and used for energy purposes and the amount of its harmful emission to the atmosphere. Direct methods are most often used to determine methane-bearing capacity. An important aspect that has a great influence on the final result of the research is the gas losses generated at the stage of sampling. Under the conditions of the Polish mining industry, the direct drill cuttings method is used to determine the methane-bearing capacity. Gas losses are compensated for in this method with the use of the coefficient 1.12, by which the obtained result is multiplied. In this paper, a multi-parameter analysis of gas loss in the determination of methane-bearing capacity in hard coal seams has been carried out. Several experiments were performed to identify the most important aspects to be taken into account to obtain a correct result. A methane-bearing capacity test was conducted using two direct methods: the direct drill cuttings method, otherwise known as the single-phase vacuum degassing method, and a method based on the United States Bureau of Mines standards. Sorption studies, such as methane sorption kinetics tests, were also conducted in which sorption properties, such as sorption capacity, effective diffusion coefficient, and half sorption time, were determined. Methane sorption isotherms were also determined, and pore structure was analysed. Based on the obtained test results, an analysis was carried out which made it possible to present appropriate conclusions concerning the gas losses during the methane-bearing capacity test, generated at the stage of sampling. The final result of the work was the proposal of a new gas loss coefficient for the direct drill cuttings method of methane-bearing capacity determination.

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