The current study aims to investigate the influence of iron minerals on the amorphous phase content, compressive strengths and the microstructural properties of the geopolymer materials. Geopolymer materials were prepared by the substitution of metakaolin by 10 and 20 wt.% of each iron mineral sample. Sodium waterglass from rice husk ash was used as a hardener, and metakaolin was used as an aluminosilicate source. The X-ray patterns show that the iron minerals denoted FR and FB are associated with hematite and magnetite, respectively. FY contains goethite together with a significant content of kaolinite and quartz. It is observed in the XRD patterns and FTIR absorption spectra that the additions of hematite, magnetite and goethite remain largely unreacted in the geopolymer binder. The compressive strengths of the related geopolymer composites show some significant variations indicating certain effects for mechanical stability obtained: 10 wt.% replacement of metakaolin by hematite increased the compressive strength from 51.1 to 55.5 MPa, while 20 wt.% hematite caused a decrease to 44.9 MPa. Furthermore, 10 and 20 wt.% replacement with FB revealed decreased values 47.0 and 40.3 MPa, respectively. It was also found that 10 and 20 wt.% of FY caused lower values of 30.9 and 39.1 MPa, respectively. The micrographs of geopolymer materials present some voids and cracks. The denser matrix is related to a superior gel formation producing a better glue between the crystalline additions. The unsubstituted geopolymer sample provides with about 50% the highest X-ray-amorphous content, whereas the substituted samples range between 35 and 45%, indicating systematically smaller gel contents without any clear trend with the compressive strength variation, however. The strength dependencies reveal more complex interaction between the gel and crystalline additions.