Many inland waters exhibit complete or partial desiccation, or have vanished due to global change, exposing sediments to the atmosphere. Yet, data on carbon dioxide (CO 2) emissions from these sediments are too scarce to upscale emissions for global estimates or to understand their fundamental drivers. Here, we present the results of a global survey covering 196 dry inland waters across diverse ecosystem types and climate zones. We show that their CO 2 emissions share fundamental drivers and constitute a substantial fraction of the carbon cycled by inland waters. CO 2 emissions were consistent across ecosystem types and climate zones, with local characteristics explaining much of the variability. Accounting for such emissions increases global estimates of carbon emissions from inland waters by 6% (~0.12 Pg C y −1). Our results indicate that emissions from dry inland waters represent a significant and likely increasing component of the inland waters carbon cycle.
Defining natural background levels (NBL) of geochemical parameters in groundwater is a key element for establishing threshold values and assessing the environmental state of groundwater bodies (GWBs). In the Apulia region (Italy), carbonate sequences and clastic sediments host the 29 regional GWBs. In this study, we applied the Italian guidelines for the assessment of the NBLs, implementing the EU Water Framework Directive, in a south-European region characterized by the typical Mediterranean climatic and hydrologic features. Inorganic compounds were analyzed at GWB scale using groundwater quality data measured half-yearly from 1995 to 2018 in the regional groundwater monitoring network (341 wells and 20 springs). Nitrates, chloride, sulfate, boron, iron, manganese and sporadically fluorides, boron, selenium, arsenic, exceed the national standards, likely due to salt contamination along the coast, agricultural practices or natural reasons. Monitoring sites impacted by evident anthropic activities were excluded from the dataset prior to NBL calculation using a web-based software tool implemented to automate the procedure. The NBLs resulted larger than the law limits for iron, manganese, chlorides, and sulfates. This methodology is suitable to be applied in Mediterranean coastal areas with high anthropic impact and overexploitation of groundwater for agricultural needs. The NBL definition can be considered one of the pillars for sustainable and long-term groundwater management by tracing a clear boundary between natural and anthropic impacts.
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