Please cite this article as: Lorevice, M.V., Otoni, C.G., Moura, M.R.d., Mattoso, L.H.C., Chitosan nanoparticles on the improvement of thermal, barrier, and mechanical properties of high-and low-methyl pectin films, Food Hydrocolloids (2015), ABSTRACT 26Non-biodegradable food packaging materials has caused serious environmental 27 problems due to their inappropriate discard. Biodegradable and renewable polymers 28 (e.g., polysaccharides), when reinforced with nanostructures, have been used to produce 29 novel, eco-friendly food packaging as alternatives to replace conventional packaging.
30This study aimed at adding chitosan nanoparticles (CSNPs) to pectin (high or low 31 methoxyl degree) matrices to produce HDM pectin/CSNP and LDM pectin/CSNP 32 nanocomposites films, as well as at evaluating the effect of CSNPs on films' 33 mechanical, thermal, and barrier properties. Also, CSNPs were characterized as to zeta 34 potential, average diameter, and FT-IR, whereas nanocomposites' thickness, 35 appearance, structure, morphology, mechanical, thermal, and barrier properties were 36 analyzed. CSNPs presented average diameter and zeta potential near to 110 nm and 50 37 mV, respectively. The addition of CSNPs improved the mechanical properties, being 38 tensile strength the most affected mechanical attribute (increased from 30.81 to 46.95 39 MPa and from 26.07 to 58.51 MPa for HDM pectin/CSNP and LDM pectin/CSNP, 40 respectively). These results show that the produced pectin/CSNPs nanocomposites had 41 improved mechanical properties when compared with control pectin films, allowing 42 these novel materials an alternative to food packaging production.43 44