Hydrogen as carbon-free fuel is a very promising candidate for climate-neutral internal combustion engine operation. In comparison to other renewable fuels, hydrogen does obviously not produce CO2 emissions. In this work, two concepts of hydrogen internal combustion engines (H2-ICEs) are investigated experimentally. One approach is the modification of a state-of-the-art gasoline passenger car engine using hydrogen direct injection. It targets gasoline-like specific power output by mixture enrichment down to stoichiometric operation. Another approach is to use a heavy-duty diesel engine equipped with spark ignition and hydrogen port fuel injection. Here, a diesel-like indicated efficiency is targeted through constant lean-burn operation. The measurement results show that both approaches are applicable. For the gasoline engine-based concept, stoichiometric operation requires a three-way catalyst or a three-way NOX storage catalyst as the primary exhaust gas aftertreatment system. For the diesel engine-based concept, state-of-the-art selective catalytic reduction (SCR) catalysts can be used to reduce the NOx emissions, provided the engine calibration ensures sufficient exhaust gas temperature levels. In conclusion, while H2-ICEs present new challenges for the development of the exhaust gas aftertreatment systems, they are capable to realize zero-impact tailpipe emission operation.

Besides electrification of the powertrain, new synthetic alternative fuels with the potential to be produced from renewable sources come into focus. Methanol is the most elementary liquid synthetic fuel and no novelty for use in internal combustion engines. This article presents pathways to achieve high efficiency spark-ignition methanol combustion on a direct injection spark-ignition single-cylinder research engine with two different stroke-to-bore ratios (1.2 and 1.5) and a constant bore. In addition, two compression ratios (CRs) were investigated on each setup: CR = 10.8 using RON95 E10 gasoline fuel and a higher CR = 15 using neat methanol. In contrast to previous studies of stroke-to-bore ratio influences on SI combustion, this article aims at demonstrating how the advantages of a high stroke-to-bore ratio can be exploited by combining a long-stroke engine with increased compression ratios and methanol. The increased stroke enhances the tumble motion due to a higher piston speed and a larger compression volume which improves the mixture homogenization and combustion velocity. Moreover, the lower surface/volume ratio results in a reduced heat transfer. When using RON95E10 gasoline fuel and CR = 10.8, an efficiency gain of up to 1.6% could be achieved with the long-stroke compared to the short-stroke especially at lower engine loads. With methanol and CR = 15, an efficiency gain of up to 1.6% could be achieved with the long-stroke setup compared to the short-stroke engine. Subsequently, lean burn conditions were experimentally investigated with methanol and CR = 15. The longer stroke allowed the lean burn limit to be extended from λ = 1.9 to λ = 2.0 with an efficiency gain of up to 2.2%. A maximum indicated efficiency of 47.4% could be achieved at λ = 1.9 with methanol on the long-stroke engine with CR = 15.

Aiming to achieve the highest combustion efficiency and less pollutant emission, a catalytic coating for cylinder walls in internal combustion engines was developed and tested under several conditions. The coating consists of a La0.8Sr0.2CoO3 (LSCO) catalyst on an aluminum-based ceramic support. Atomic force microscopy was applied to investigate the surface roughness of the LSCO coating, while in situ diffuse infrared Fourier transform spectroscopy was used to obtain the molecular understanding of adsorption and conversion. In addition, the influence of LSCO-coated substrates on the flame quenching distance was studied in a constant-volume combustion chamber. Investigations conclude that an LSCO coating leads to a reduction of flame quenching at low wall temperatures but a negligible effect at high temperatures. Finally, the influence of LSCO coatings on the in-cylinder wall-near gas composition was investigated using a fast gas sampling methodology with sample durations below 1 ms. Ion molecule reaction mass spectrometry and Fourier transform infrared spectroscopy revealed a significant reduction of hydrocarbons and carbon monoxide when LSCO coating was applied.

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