UV-active cellulose fibers were obtained by dry-wet method spinning an 8 % by weight acellulose solution in N-methylomorpholine-N-oxide (NMMO) modified by europium-doped gadolinium oxyfluoride Gd 4 O 3 F 6 :Eu 3? containing 5 mol (%) of the dopant. Photoluminescent nanoparticles were introduced in the in powder form into a polymer matrix during the process of cellulose dissolution in NMMO. The dependencies of emission intensity on excitation energy and the concentration of Gd 4 O 3-F 6 :Eu 3? nanoparticles in the final cellulosic products were examined by photoluminescence spectroscopy (excitation and emission). The fiber structure was studied by X-ray powder diffraction analysis. The size and dispersity of the nanoparticles in the polymer matrix were evaluated using scanning electron microscopy and X-ray microanalysis. The influence of different concentration particles (in the range from 0.5 to 5 % by weight) on the mechanical properties of the fibers, such as tenacity and elongation at break, were determined.
This paper describes a method for manufacturing luminescent cellulose fibers. Good optical properties of cellulose fibers under UV-C illumination were achieved by incorporating ZrO 2 (0.5 mol% of Eu 3? ) stabilized by Y 2 O 3 (7 mol%) into the fiber structure's particles. Fibers were obtained from 8 wt% cellulose solution in N-methylmorpholine N-oxide (NMMO) with the addition of a luminescent modifier in the range between 0.5 and 10 wt%. The physicochemical and mechanical parameters and the structure of these fibers were examined.
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