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Within the framework of the bilateral CORNET projects MeTexCom and MeTexCom2, new approaches were developed and tested to improve the adhesion strength of metal textile composites, with a focus on the targeted roughening of aluminum surfaces and the development of new acoustically insulating nonwovens. The metal textile composites were produced by melting thermoplastic components of the textile composites without a separately applied adhesive.For improved adhesion strength between metal and textile, roughness was generated on the metal surface by means of a novel arc treatment by an anodic polarized TIG process or a cw (continuous wave) fiber laser process. On the one hand, the goal was to produce uniformly rough, untercut surface structures in micro-and nanodimension by means of a highly dynamic arcing process. On the other hand, a similar approach was pursued with the cw laser method by using a single-mode as well as a multi-mode laser.

Co-continuous blend systems of polycarbonate (PC), poly(styrene-co-acrylonitrile) (SAN), commercial non-functionalized multi-walled carbon nanotubes (MWCNTs) or various types of commercial and laboratory functionalized single-walled carbon nanotubes (SWCNTs), and a reactive component (RC, N-phenylmaleimide styrene maleic anhydride copolymer) were melt compounded in one step in a microcompounder. The blend system is immiscible, while the RC is miscible with SAN and contains maleic anhydride groups that have the potential to reactively couple with functional groups on the surface of the nanotubes. The influence of the RC on the localization of MWCNTs and SWCNTs (0.5 wt. %) was investigated by transmission electron microscopy (TEM) and energy-filtered TEM. In PC/SAN blends without RC, MWCNTs are localized in the PC component. In contrast, in PC/SAN-RC, the MWCNTs localize in the SAN-RC component, depending on the RC concentration. By adjusting the MWCNT/RC ratio, the localization of the MWCNTs can be tuned. The SWCNTs behave differently compared to the MWCNTs in PC/SAN-RC blends and their localization occurs either only in the PC or in both blend components, depending on the type of the SWCNTs. CNT defect concentration and surface functionalities seem to be responsible for the localization differences.

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