In the Valle dei Templi in Agrigento seven Doric temples stand lengthwise the crest of a rigid calcarenite cuesta over a layer of carbonate sand which lies along a thick stratum of clays. The environment is highly prone to landslides since topplings of calcarenite blocks often occur. The rock slopes are moving back and the slope edge draw near to the foundation of the Temple of Hera Lacinia contributing to increase their perilous condition. To assess the role of unsaturated sands in the instability processes, after the compositional and textural analysis of the material, direct shear tests and oedometer tests have been carried out on sand samples initially at the natural state, with low or very low values of natural water content, and finally at higher values of the saturation degree.The mechanical behaviour of sands seems one of the main causes of the instability influenced by the presence of an open metastable structure, which develops through bonding mechanisms generated via suctions and/or through cementing material such as clay or salts.

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This paper deals with the compositional and textural characteristics determining open metastable structures in the pleistocenic sand outcropping in the Agrigento district (Sicily). The aim of the study was to individuate the bonding types occurring between grains that could generate matric suction phenomena. The composition and microfabric were characterised by means of granulometry, porosimetry, permeability, optical and ESEM-EDS microscopy, thermogravimetry and XR diffractometry, electric conductivity, and ionic chromatography. The data thus acquired show that the skeleton of the sand is constituted mostly by bioclasts and microfossils, calcite and quartz monocrystalline grains. Moreover, assemblages of silt and clay minerals are interposed among them. Cementation is generally absent even at the sites of contact between grains. Porosity is due mainly to interparticle voids. The spatial arrangement of sand, silt and limey grains, the pore geometry, volume and size distribution and network connectivity allow both capillary condensation and effective capillary transport of water. It appears that bonding is due mainly to capillary forces related to the texture and to the type of pores rather than being ruled by composition.

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