The
excess of mango peels is considered manufacturing waste in
the sugar and juice industry. There is an increasing interest in looking
for alternative ways to employ this waste to address this overload.
Here, we show the efficient use of mango peels as a noncost carbon
source for the synthesis of graphene. We demonstrate for the first
time the synthesis of graphene on Cu substrates from mango peels,
a biomass rich in pectin. It is observed that plasma presence is essential
for the growth of graphene from mango peels. At 15 and 30 min of plasma
exposure, we observed the presence of multilayered graphene, at longer
plasma exposure, i.e., 60 min, there is the formation of monolayer
graphene, attributed to the etching of multiple layers formed at short
times due to long plasma exposure time. When employing this technique,
precautions must be taken due to the etching effect of plasma, such
as reducing either the plasma exposure time or the plasma power. Finally,
we present a graphene growth pathway under plasma environment on the
basis of our experimental observations.
The microstructural changes due to the aging process in steel pipeline weldments as a function of the thermoelectric power (TEP) were studied. In general, the thermoelectric methods are based on the well-known Seebeck effect. The thermoelectric methods monitor the TEP via an electron flux induced by a temperature gradient in metallic materials, which is affected by the different types of defects that are present in the atomic lattice, such as atoms in the solid solution, precipitates and dislocations. In this present study, the relationship among the TEP data, hardness and the microstructure of steel pipeline weldments was investigated. In addition, the coarse and dendritic grain structure of the welding material is extremely and unpredictably anisotropic. Such microstructures are no longer direction-independent to the electron flux. Therefore, it has an opposite negative effect on the TEP and overlaps the precipitation effect due to the aging process. TEP and hardness measurements were obtained in each zone of the weldments. For each section of the weldment, the weld bead (WB), heat affected zone (HAZ) and base metal (BM) were found to correspond to particular values of TEP. The relationship between the TEP and the microstructure of a weldment of X60 and X65 micro-alloyed steel that was artificially aged was obtained using the conventional contact TEP technique (hot-tip) and scanning electron microscopy (SEM). It was found that thermoelectric power is very sensitive to the aging process in the two-studied steel pipeline weldments.
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