In this study, binary blends of biodegradable polymers were prepared to improve the ductile properties of those that have a more rigid and/or brittle. Specifically, PLA, PHA and TPS were blended with different amounts of PBS with the objective of reducing the stiffness and brittleness of the three polymers. The compatibility of the blends and their resulting mechanical properties were studied. The flexibility of the blends increased with the addition of PBS; however, a limited compatibility was achieved, leading to a low impact resistance improvement. For this reason, other blend options with an EVA-based material were studied, increasing the impact resistance and flexibility of the PLA material in this case.