Densities (r) and viscosities (h) of the binary systems 2-Methoxy-2-methylpropane with n-propanol were measured at temperatures 288.15, 293.15, 298.15, 303.15 and 308.15 K and atmospheric pressure, over the whole composition range. Belda, Herraez, Emmerling et al. and Gonzalez-Olmos-Iglesias models were used to correlate the densities of binary mixtures. The Mchaweh-Nasrifar-Mashfeghian, Hankinson-Thomson, Yamada-Gunn and Reid et al. models were used to estimate the liquid density of the binary mixtures. Viscosity results were fitted to the equations of Grunberg-Nissan, Heric-Brewer, Jouyban-Acree and McAllister. The thermodynamic activation parameters, free energy, DG�, enthalpy, DH� and entropy, DS� for viscous flow have been estimated and their variations with compositions have been discussed.
Densities and viscosities of the binary systems dimethylsulfoxide with diethylene glycol and methyldiethanolamine were measured at temperatures ranging from 293.15 to 313.15 K, at atmospheric pressure and over the entire composition range. The experimental density data was correlated as a function of composition using Belda’s and Herraez’s equations, and as a function of temperature and composition using the models of Emmerling et al. and Gonzalez-Olmos-Iglesias. The viscosity results were fitted to the Grunberg-Nissan, Heric-Brewer, Wilson, Noda, and Ishida and Eyring-NRTL equations. The values of viscosity deviation (), excess molar volume (VE), partial molar volumes ( and ) and apparent molar volume ( and ) were determined. The excess functions of the binary systems were fitted to the polynomial equations. The values of thermodynamic functions of activation of viscous flow were calculated and discussed.
Densities (r) and viscosities (h) of the binary systems 2-Methoxy-2-methylpropane with iso-propanol were measured at temperatures (288.15, 293.15, 298.15, 303.15 and 308.15) K and atmospheric pressure, over the whole composition range. The density and viscosity of the solutions were correlated with the temperature with a linear equation, respectively with Guzman�s equation. The excess values of molar volume (VE), viscosity (hE) and molar Gibbs energy (DG*E) were calculated from experimental measurements. The excess functions of the binary systems were fitted to Redlich-Kister equation. Viscosity results were fitted to the equations of Grunberg-Nissan, Heric-Brewer, Jouyban-Acree and McAllister.
Densities (ρ) and viscosities (η) of the binary systems n-heptane with alcohols (ethanol, propan-1-ol and propan-2-ol) were measured at temperatures between 288.15 and 308.15 K and at atmospheric pressure, over the whole composition range. The excess values of molar volume (V E) and viscosity (η E) were calculated from experimental measurements. The excess functions of the binary systems were fitted to Redlich-Kister Equation. Comparison between experimental excess molar volume and the one calculated from Flory and Prigogine-Flory-Patterson theories, has also been done. The viscosity results were fitted to the equations of Grunberg-Nissan, Heric-Brewer, Jouyban-Acree and McAllister. Also, the activation energies of viscous flow have been obtained and their variations with compositions have been discussed.
This paper reports propertiesdata at 20, 25 and 30 0C and 1 atmosphere pressure for diethylene glycol dibutyl ether - ethanol system depending on concentration. The experimental values of density and viscosities of pure components and mixtures were correlated with temperature. The excess properties were determined from experimental data of densities and viscosities. These excess values were correlated to Hwang and Redlich-Kister equations. The value of excess molar volume for equimolar solution was compared with the values calculated from the Flory and Prigogine-Flory-Patterson theories.
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