Abstract. In this work, we present new results of Atomic Force Microscopy (AFM) force curves over pure ice at different temperatures, performed with two different environmental chambers and different kind of AFM tips. Our results provide insight to resolve the controversy on the interpretation of experimental AFM curves on the ice-air interface for determining the thickness of the quasi-liquid layer (QLL). The use of a mini environmental chamber, that provides an accurate control of the temperature and humidity of the gases in contact with the sample, allowed us for the first time to get force curves over 15 the ice-air interface without jump-in (jumps of the tip onto the ice surface, widely observed in previous studies). These results suggest a QLL thickness below 1 nm within the explored temperature range (-7 ºC to -2 ºC). This upper bound is significantly lower than most of the previous AFM results, which suggests that previous authors overestimate the equilibrium QLL thickness, due to temperature gradients, or indentation of ice during the jump-in. Additionally, we proved that the hydrophobicity of AFM tips affects significantly the results of the experiments. Overall, this work shows that, if one 20 chooses properly the experimental conditions, the QLL thicknesses obtained by AFM lay over the lower bound of the highly disperse results reported in the literature. This allows estimating upper boundaries for the QLL thicknesses, which is relevant to validate QLL theories, and to improve multiphase atmospheric chemistry models.

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