SEM–EDS, EMPA, ICP–MS and ICP–OES were applied to the study of three sectilia panels made of red, orange and yellow glass slabs. In order to determine the chemical state of Cu, XAS was also performed. The results indicate that, with the exception of the red samples, all slabs were made by mixing a siliceous sand with natron. The red slabs show significant compositional differences with respect to K2O and MgO contents, probably linked to the use of plant ashes as a source of alkali. The red, orange and yellow slabs are coloured by metallic copper, cuprite and Pb antimonates, respectively. The comparison between the chemical composition of the Faragola samples and several glass reference groups did not provide conclusive evidence of provenance.
Archaeological excavation at the San Giusto site (Lucera, Italy) has unearthed a Late Antique kiln that was most certainly dedicated to the production of cooking ware. An archaeometric study of numerous specimens of cooking and painted ware found at this site was carried out using optical microscopy, scanning electron microscopy, micro-Raman spectroscopy, X-ray diffraction, X-ray fluorescence, inductively coupled plasma mass and optical emission spectrometry and instrumental neutron activation analysis. The integration of historicalarchaeological data with archaeometric data has revealed that these specimens can be attributed to the San Giusto site. Furthermore, the production cycle of this ware can thus be reconstructed: from the diversified supply of raw materials (fluvial and marine sediments), to the relatively complex preparation of the paste, to firing at variable temperatures (600-750 ° C for cooking ware; 850 -1050 ° C for painted ware).
Analyses at the Cu–K, Fe–K and Mn–K edge were performed to study the green, marbled (green and yellow), blue and blackish (deep greyish olive green) glass slabs decorating three sectilia panels from the archaeological site of Faragola. Results indicate that all slabs were made by mixing siliceous sand with natron, sometimes probably mixed with small percentages of plant ash. Cu2+ and Pb antimonates should be responsible for the opaque green colours. The dark green and yellow portions of the marbled slabs are respectively comparable to the slabs comprising only one of these colours. Cu2+ together with Ca antimonates probably produced light blue slabs, whereas cobalt was used to produce dark blue slabs. We consider it possible that the abundance ratio of Fe2+/Fe3+ and the complex Fe3+S2− would have an effect on the blackish slabs. The contribution of Mn cannot be ascertained even if it could have played a role in darkening glass colour. The comparison between the chemical composition of Faragola samples and several glass reference groups provided no conclusive evidence of provenance; whereas, the presence of a secondary local workshop can be hypothesized.
In the framework of the archaeometric research on Apulian Late Antique glass, a collection of 24 glass vessels (third to seventh centuries ad) and production indicators found at Herdonia (Foggia, Italy) was examined, by means of SEM–EDS, EMPA, ICP–MS and LA–ICP–MS. A fragment of crucible was further investigated by SEM–EDS and EMPA. The results obtained were discussed together with another glass collection from Herdonia previously investigated. The full set of 48 samples was made of siliceous sands mixed with plant ashes (two samples: a dark green slab and a colourless beaker/lamp) or natron (all the other 46 samples). The latter were assigned to the following compositional groups: HIMT, Levantine 1, RNCBGY1, RNCBGY2, RC/LAC‐Sb, intermediate HIMT/RNCBGY1, intermediate RNCBGY1/HIMT, intermediate Levantine/RNCBGY2 and two other groups, the CaO‐rich HIMT and the CaO‐rich/Na2O poor HIMT, which showed a prevailing Adriatic distribution and a close similarity to the weak HIMT glass group. Most Herdonia samples were similar to the HIMT productions, and thus of likely Egyptian origin, while a smaller number of samples referred to the Levantine productions.
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