In recent years proof of "indoor air quality", designed to protect and improve the health and safety of workers, was a central strategy in the prevention of many companies. The man creates with the environment in which he lives and works a continuous gas exchange through breathing; this makes the respiratory system main entrance of air pollutants. The indoor pollutants are numerous and originate from different sources. Their concentration may vary over time and depends on the nature of the source, on ventilation, habits and activities carried out by the occupants in the areas concerned. It is well known that photocopiers and laser printers are equipment that emit several chemicals (ozone, solvents, toner dust) both to release the materials used for their operation (toner, ink, paper) and then to the special printing technology used. During the printing and photocopying processes occurring chemical and physical processes complex, during which the components of toner and paper will react under the influence of light and high temperatures. More recently, there have been a growing number of articles as a result of indoor air pollution. They have become more and more significant; probably because of increasing of the concentrations of harmful substances in the confined environment. Particular attention has been given to the emission of harmful substances from electronic equipment and printing that are increasingly present in living and working place. This work was the main objective the emission of volatile organic compounds, formaldehyde and ozone from laser printing devices and consequently the estimation of elimination of same substances through a paper filters which operate through a mechanism of filtration surface with interstitial and penetration of particles into matrix filter on agglomeration, they also enclose type sandwich a layer of activated carbon.
Dermal exposure of workers to pesticides can be assessed using patches, placed on the workers’ clothes or used to wipe off the substance from the skin. Since there are no official indications of the materials to be used for patch sampling, a wide range of materials is suggested in the scientific literature. This paper reports a laboratory study on the affinity of four different pesticides widely used in southern Italy with five patch matrices. Imidacloprid, Hexythiazox, Boscalid and Myclobutanil were tested with cotton and gauze sheets, polyethylene tissue and two different grades of cellulose papers. An aerosol machine was used to nebulize the substance on the patches in a closed system, simulating the conditions of use on the workers’ clothes. The recovery of the analytes from the media was evaluated, by spiking the patches with a known amount of each active substance and testing their performances as skin wipes. Samples were extracted and analyzed in gas chromatography with an electron capture detector. The recovery from the spiked patches was 89–96% for all pesticides, while the test recoveries were very different. Results showed a higher affinity with Imidacloprid and Hexythiazox for gauze, with Myclobutanil for cotton and with Boscalid for paper filters (W41).
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