Hemp fibres used as a reinforcing agent and three polymeric matrices (polypropylene, bicomponent, recycled polyester) were used to obtain composite materials by needle punching and heat pressing. The influence of the hemp/matrix ratio and the nature of the matrix on the properties of the composites were analysed. The obtained composites were characterised by physical–mechanical indices, thermal analysis (thermogravimetry (TG), differential thermogravimetry (DTG) and Differential Scanning Calorimetry (DSC)), Fourier Transform Infrared Spectroscopy (FTIR-ATR) analysis, Scanning Electron Microscopy (SEM) and Chromatic measurements. The mechanical properties of composites are influenced by both the hemp/matrix ratio and the nature of the matrix. The thermal stability of composites decreased as the amount of hemp increased (for the same mass losses, the decomposition temperature decreased significantly for composites containing a quantity of hemp greater than 50%). Regarding the nature of the matrix, for the same mass loss, the highest decomposition temperature was presented by the composites containing recycled polyester as matrix, and the lowest one was presented by composites containing polypropylene fibres as matrix. The FTIR and SEM analyses highlight the changes that occurred in the structure of the composite, changes determined both by the amount of hemp in the composite and by the nature of the matrix.
In recent years, the growth of environmental awareness has increased the interest in the development of biocomposites which are sustainable materials with an excellent price–performance ratio and low weight. The current study aimed to obtain and characterize the biocomposites prepared by thermoforming using coir fibres as reinforcing material and polypropylene as matrix. The biocomposites were produced with different coir fibres/polypropylene ratios and were characterized by physical–mechanical indices, thermal analysis, crystallinity, attenuated total reflection-Fourier transform infrared spectroscopy analysis (ATR-FTIR), scanning electron microscopy (SEM), and chromatic measurements. Both tensile and bending strength of biocomposites decreased when the coir fibre content increased. The melting temperature of biocomposite materials has decreased with the increase of the coir fibre loading. Regarding the thermal stability, the weight loss and degradation temperature increased with decreasing coir fibre content. The ATR-FTIR and SEM analyses underlined the modifications that took place in the structure of the biocomposites by modifying the coir fibres/matrix ratio.
In this study, polypropylene-based thermoformed composites have been obtained using polyester woven fabric scraps
as reinforcement. Four types of matrix have been used for the experiments: biaxially oriented polypropylene bag waste
(BOPP), polypropylene nonwoven waste (TNT), 50/50 BOPP/TNT waste and virgin polypropylene fibres (PP). The
percentage of matrix has been varied at four levels: 20%, 30%, 40%, and 50%. The effect of matrix/reinforcement mass
ratio and matrix type on the mechanical properties of composite materials has been studied. Since the composite
materials are intended to replace the oriented strand boards (OSB) in construction and furniture applications,
comparison with the characteristics of 8 mm OSB has been made.
Waste recycling is a solution that reduces the environmental impact of waste landfilling or incineration. The aim of this paper is to investigate both the effect of incorporating recycled fibers obtained by defibrating 50/50 hemp/rPP nonwoven waste and the effect of the compatibilizer on the properties of composite materials. Composites incorporating 50% and 100% recycled fibers were treated with 2.5% and 5% maleated polypropylene (MAPP), respectively, and compared to both the untreated composites and the composite obtained by thermoforming from the nonwovens that generated the waste. The incorporation of 50% and 100% recycled fibers into composites decreased the tensile strength by 17.1–22.6%, the elongation at break by 12.4–20.1%, the flexural strength by 6.6–9%, and flexural modulus by 10.3–37%. The addition of 5% MAPP showed the greatest improvements in mechanical properties of composites containing 100% recycled fibers, as follows: 19.2% increase in tensile strength, 3.8% increase in flexural strength, and 14.8% increase in flexural modulus. Thermal analysis established that at temperatures ranging between 20 °C and 120 °C, the composites were thermally stable. SEM analysis revealed good coverage of the reinforcing fibers, and EDX analysis confirmed the presence of the compatibilizing agent in the structure of the composite material.
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