Geochemical and mineralogical characterization studies play an important role in the definition of mineral deposits. Each mineral system has a unique set of minerals with different chemical makeup and physical properties. Platinum-group elements (PGEs), for example, are scarce resources with many applications. The optimization of extraction process efficiency is therefore crucial to prevent resource shortage and increased bulk prices. To improve the mineral liberation process, high throughput sensors must be added alongside the production line as part of fast process analysis implementation. Current analytical methods are either ineffective to assess PGE content, or unusable in the conditions of the processing facilities. This article shows how Laser-induced breakdown spectroscopy (LIBS) technology, developed by ELEMISSION Inc, can circumvent these drawbacks by enabling automated, ultra-fast, and precise quantitative mineral analyses in any working environment. The drill core samples that were used in this study were collected at the Stillwater platinum group element mine in the United States. The data used for the mineralogical database was validated using the TESCAN Integrated Mineral Analyzer (TIMA) instrument.
Scarce platinum group elements (PGE) are mainly concealed in massive sulfides, and finding economically viable ore bodies largely relies on their fast chemical mapping. Most core scanners provide incomplete mineralogical contents, but none also provide a complete chemical analysis including light elements. This study investigates the performance of a fully automated laser-induced breakdown spectroscopy (LIBS) core scanner, the ECORE, by comparing its reliability to a scanning electron microscope-energy dispersive spectroscopy (SEM-EDS) mineral mapper and its speed to infrared diffuse reflectance hyperspectral imagers (IR-HSI). The LIBS elemental imaging has been put to the test in our previous work, as well as the high-resolution mineralogical mapping. This paper reports the scaling up analytical applicability of LIBS as a high performance and high-speed drill core scanner. The analysis of a full core tray in this study is the first and largest 7.62 megapixels image done by a LIBS core scanner to our knowledge. Both high-resolution and low-resolution data are put together to express both mineralogical and chemical content as a function of depth.
Laser-induced breakdown spectroscopy (LIBS) is a valuable tool for the solid-state elemental analysis of battery materials. Key advantages include a high sensitivity for light elements (lithium included), complex emission patterns unique to individual elements through the full periodic table, and record speed analysis reaching 1300 full spectra per second (1.3 kHz acquisition rate). This study investigates deep learning methods as an alternative tool to accurately recognize different compositions of similar battery materials regardless of their physical properties or manufacturer. Such applications are of interest for the real-time digitalization of battery components and identification in automated manufacturing and recycling plant designs.
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