Supercritical carbon dioxide (scCO 2 ) technology was used for preparation of functional pH sensitive chitosan-based aerogels characterized with micron size pores and their impregnation with thymol as a natural bioactive substance. Hydrogels based on chitosan, itaconic and methacrylic acids were transformed to alcogels and dried in the air or with scCO 2 to obtain xero-and aerogels, respectively. Applying 10 min of static and 120 min of dynamic scCO 2 drying at 11 MPa and 458C followed with the decompression at a rate of 1 MPa/min yielded an advantageous aerogel with favorable swelling kinetics and elasticity, compared to the xerogel and aerogels obtained at other decompression rates and drying times. This aerogel was successfully loaded with thymol (up to 4.6 wt.%) using supercritical scCO 2 at 10 MPa and 358C. In vitro studies of swelling in PBS at 378C indicated a great potential of the obtained stimuli-responsive chitosan gels for topical administration of thymol known for antimicrobial, antioxidant and anti-inflammatory activities. POLYM. ENG. SCI., 00:000-000,

The present paper reports on pectin based films modified with carboxymethyl cellulose intended for food packaging. The films are prepared by solvent‐casting method with different carboxymethyl cellulose content and cross‐linker concentration (Ca2+ ions) in the presence of glycerol as a plasticizer. FT‐IR spectra of the prepared films propose that carboxyl group from pectin are mainly involved in interactions with CMC, whereas −OH groups are mainly involved in self‐associated hydrogen bonding of neat polymers. Further, an addition of carboxymethyl cellulose improved mechanical properties compared to pure pectin films, while TGA analysis confirmed satisfying thermal stability regarding their potential application as packaging material. Finally, water vapor permeability values are in the range of 1.32 × 10−7 up to 2.03 × 10−7 g/m h Pa.

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An interpenetrating polymer network (IPN) based on the sodium alginate (A) and partially neutralized poly(methacrylic acid) (MAA) was prepared by free radical polymerization followed by additional cross‐linking of sodium alginate with calcium ions. Obtained material (A/MAA IPN) was characterized by FTIR spectroscopy, thermogravimetric analysis, scanning electron microscopy, and rheological measurements. Swelling behavior of synthetized IPN has been also investigated. TiO2 nanoparticles (TiO2 NPs) were immobilized onto A/MAA IPN by dip‐coating method and obtained TiO2/IPN nanocomposite was used for removal of the methylene blue (MB) from aqueous solution. The photodegradation (under illumination) and sorption (in the dark) processes for dye removal were monitored through decrease of dye concentration in the solution by UV/VIS spectrometer. The TiO2/IPN nanocomposite sorbed approximately 93% of the MB from a 10 mg L−1 MB solution in the dark, but no degradation occurred. Likewise, more than 93% of dye was removed after 8 h of illumination. However, after 24 h of illumination, the samples were discolored indicating that dye molecules were successfully degraded. Thus, the TiO2/IPN nanocomposite could be utilized in the photodegradation–sorption process for the abatement of pollutants in water. POLYM. ENG. SCI., 55:2511–2518, 2015. © 2015 Society of Plastics Engineers

Stimuli responsive pH- and temperature-sensitive hydrogel drug delivery systems, as those based on N-isopropylacrylamide (NiPAAm) and itaconic acid (IA), have been attracting much of the attention of the scientific community nowadays, especially in the field of drug release. By adjusting comonomer composition, the matrix is enabled to protect the incorporated protein in the highly acidic environment of upper gastrointestinal tract and deliver it in the neutral or slightly basic region of the lower intestine. The protein/poly(NiPAAm-co-IA) hydrogels were synthetized by free radical crosslinking copolymerization and were characterized concerning their swelling capability, mechanical properties, and morphology. The pore structure and sizes up to 1.90 nm allowed good entrapment of lipase molecules. Model protein, lipase from Candida rugosa, was entrapped within hydrogels upon mild conditions that provided its protection from harmful environmental influences. The efficiency of the lipase entrapment reached 96.7%, and was dependent on the initial concentration of lipase solution. The swelling of the obtained hydrogels in simulated pH and temperature of gastrointestinal tract, the lipase entrapment efficiency, and its release profiles from hydrogels were investigated as well.