No abstract

In 2009, we identified a TCE plume at an abandoned landfill that was located in a low permeable silty-clay aquifer. To treat the TCE, we manufactured slow-release potassium permanganate cylinders (oxidant candles) that had diameters of either 5.1 or 7.6 cm and were 91.4 cm long. In 2010, we compared two methods of candle installation by inserting equal masses of the oxidant candles (7.6-cm vs 5.1-cm dia). The 5.1-cm dia candles were inserted with direct-push rods while the 7.6-cm candles were housed in screens and lowered into 10 permanent wells. Since installation, the 7.6-cm oxidant candles have been refurbished approximately once per year by gently scraping off surface oxides. In 2012, we reported initial results; in this paper, we provide a 5-yr performance review since installation. Temporal sampling shows oxidant candles placed in wells have steadily reduced migrating TCE concentrations. Moreover, these candles still maintain an inner core of oxidant that has yet to contribute to the dissolution front and should provide several more years of service. Oxidant candles inserted by direct-push have stopped reducing TCE concentrations because a MnO2 scale developed on the outside of the candles. To counteract oxide scaling, we fabricated a second generation of oxidant candles that contain sodium hexametaphosphate. Laboratory experiments (batch and flow-through) show that these second-generation permanganate candles have better release characteristics and are less prone to oxide scaling. This improvement should reduce the need to perform maintenance on candles placed in wells and provide greater longevity for candles inserted by direct-push.

No abstract

One of the biggest challenges to treating contaminated aquifers with chemical oxidants is achieving uniform coverage of the target zone. In an effort to maximize coverage, we report the design and installation of a novel aerated, slow-release oxidant delivery system that can be installed by direct-push equipment. By continuously bubbling air beneath a slow-release oxidant in situ, an airlift pump is created that causes water and oxidant to be dispersed from the top of the outer screen and drawn in at the bottom. This continuous circulation pattern around each drive point greatly facilitates the spreading of the oxidant as it slowly dissolves from the wax matrix (i.e., oxidant candle). Given that the aeration rate controls the outward flow of oxidant from the outer screen in all directions, the radius of influence around each drive point is largely a function of the outward velocity of the oxidant exiting the screen and the advection rate opposing the upgradient and lateral spreading. Temporal sampling from three field sites treated with the aerated oxidant system are presented and results show that contaminant concentrations typically decreased 50–99% within 6–9 months after installation. Supporting flow tank experiments that demonstrate oxidant flow patterns and treatment efficacy are also presented.