Recently, high-transition-temperature (high-Tc) superconductivity was discovered in the iron pnictide RFeAsO(1-x)F(x) (R, rare-earth metal) family of materials. We use neutron scattering to study the structural and magnetic phase transitions in CeFeAsO(1-x)F(x) as the system is tuned from a semimetal to a high-Tc superconductor through fluorine (F) doping, x. In the undoped state, CeFeAsO develops a structural lattice distortion followed by a collinear antiferromagnetic order with decreasing temperature. With increasing fluorine doping, the structural phase transition decreases gradually and vanishes within the superconductivity dome near x=0.10, whereas the antiferromagnetic order is suppressed before the appearance of superconductivity for x>0.06, resulting in an electronic phase diagram remarkably similar to that of the high-Tc copper oxides. Comparison of the structural evolution of CeFeAsO(1-x)F(x) with other Fe-based superconductors suggests that the structural perfection of the Fe-As tetrahedron is important for the high-Tc superconductivity in these Fe pnictides.

The new alpha-Fe(Te,Se) superconductors share the common iron building block and ferminology with the LaFeAsO and BaFe(2)As(2) families of superconductors. In contrast with the predicted commensurate spin-density-wave order at the nesting wave vector (pi, 0), a completely different magnetic order with a composition tunable propagation vector (deltapi, deltapi) was determined for the parent compound Fe_{1+y}Te in this powder and single-crystal neutron diffraction study. The new antiferromagnetic order survives as a short-range one even in the highest T_{C} sample. An alternative to the prevailing nesting Fermi surface mechanism is required to understand the latest family of ferrous superconductors.