Abstract. The refractive index of fully dense, infrared-transparent polycrystalline alumina (PCA) with a mean grain size of ∼0.6 μm is reported for the wavelength range 0.85 to 5.0 μm over the temperature range T ¼ 296 to 498 K. The temperature-dependent Sellmeier equation is.5533, and the root-mean square deviation from measurements is 0.0002. This paper describes how to predict the refractive index of fully dense isotropic PCA with randomly oriented grains using the ordinary and extraordinary refractive indices (n o and n e ) of sapphire spatially averaged over the surface of a hemisphere. The refractive index of alumina at 296 and 470 K agrees within AE0.0002 with the predicted values. Similarly, the ordinary and extraordinary optical constants k o and k e are used to predict the absorption coefficient of alumina. The refractive indices n o and n e of sapphire grown at Rubicon Technologies by the Kyropoulos method were measured at 295 K and agree with published Sellmeier equations for sapphire grown by other methods within AE0.0002.
Good dispersion of oxide ceramics in organic solvents can be achieved using many different dispersants. Several types of dispersants, including fatty acids, coupling agents, polar aromatic compounds and polymers, are discussed to illustrate the important phenomena. Many new problems arise in actual slips during ceramics processing; these are briefly discussed.
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