We propose that large, reversible shape changes in solids, of between 10%-400%, can be induced optically by photoisomerizing monodomain nematic elastomers. Empirical and molecular analysis of shape change and its relation to thermal effects is given along with a simple model of the dynamics of response. Our experiments demonstrate these effects for the first time and theory is compared qualitatively with our results.

No abstract

No abstract

No abstract

We discuss methods of reversibly inducing non-developable surfaces from flat sheets of material at the micro-scale all the way to macroscopic objects. We analyse the elastic ground states of a nematic glass in the membrane approximation as a function of temperature for disclination defects of topological charge +1. An aim is to show that by writing an appropriate director field into such a solid, one could create a surface with Gaussian curvature, dynamically switchable from flat sheets while avoiding stretch energy. In addition to the prospect of programmable structures, such surfaces offer actuation via stretch in thin systems since when illumination is subsequently removed, unavoidable stretches return.