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This paper deals with the adsorption of heavy metal ions on the surface of carbonaceous materials obtained via the chemical activation of biomass. Waste plum stones, pine sawdust and horsetail herb were used as the precursors of carbonaceous adsorbents. The effect of the precursor type and preparation procedure on the physicochemical properties of activated biocarbons and their sorption abilities towards Pb(II) and Cu(II) ions have been checked. The obtained micro-mesoporous activated biocarbons were characterized by determination of elemental composition and ash content, the number of surface functional groups and pH of water extracts as well as textural study based on low temperature nitrogen adsorption/desorption and scanning electron microscopy. Additionally, the electrokinetic studies including solid surface charge density and zeta potential determination were performed. Moreover, the adsorption data modelling (equilibrium and kinetics), XPS results analysis and comparison of parameters characterizing electrical double layer formed at the solid-liquid interface enabled the specification of the mechanism of heavy metals binding with the activated biocarbons surface. The maximum adsorption capacity towards copper and lead ions (177.5 and 178.1 mg/g, respectively) was found for plum stone-based activated biocarbon. For all carbonaceous materials, better fit to the experimental data was achieved with a Langmuir isotherm than a Freundlich one. In turn, a better fit of the kinetics data was obtained using the pseudo-second order model.

The main aim of this study was the determination of temperature influence on adsorption mechanisms of anionic poly(acrylic acid) (PAA) and cationic polyethylenimine (PEI) on the surface of activated carbons (AC) obtained via chemical activation of nettle (NE) and sage (SA) herbs. All measurements were performed at pH 3 at three temperature values, i.e., 15, 25 and 35 °C. The adsorption/desorption of these polymers from single and mixed solution of adsorbates was also investigated. The viscosity studies were additionally performed to obtain hydrodynamic radius values characterizing polymeric macromolecules conformation in the solution. These data are very important for the explanation of changes of linear dimensions of polymer chains with the rise of temperature caused by the modification of polymer–solvent interactions. Moreover, the XPS studies for the systems showing the highest adsorbed amounts in the specific temperature conditions were carried out. These were the systems containing PEI, PAA and NE–AC activated carbon at 25 °C. In such a case, the maximum adsorption capacity towards PAA macromolecules from a single solution of adsorbate reaches the value of 198.12 mg/g. Additionally, the thermodynamic parameters including the free energies of adsorption, as well as changes in free enthalpy and entropy were calculated.