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Fluid inclusions, mineral thermometry and stable isotope data from two types of mineralogically and texturally contrasting pegmatites, barren ones and lithium ones, from the Moldanubian Zone of the Bohemian Massif were studied in order to constrain P-T conditions of their emplacement, subsolidus hydrothermal evolution and to estimate composition of the early exsolved fluid and that of the parental melt. Despite the fact that the lithium pegmatites are abundant throughout the crystalline units of the Bohemian Massif, data similar to this paper have not been published yet. The studied pegmatites are hosted by iron-rich calcic skarn bodies. This specific setting allowed scavenging of calcium, fluorine and some other elements from the host rocks into the pegmatitic melts and postmagmatic fluids. Such contamination process was important namely in the case of barren pegmatites, as can be deduced from the variation in anorthite contents in plagioclase and from the presence of fluorite, hornblende (with F content) or garnet in the contact zones of pegmatite dykes. Fluid inclusions were studied mostly in quartz, but also in fluorite, titanite and apatite. Early aqueous-carbonic and late aqueous fluids were identified in both pegmatite types. The P-T conditions of crystallization as well as the detailed composition of exsolved magmatic fluid, however, particularly differ. The magmatic fluids associated with barren pegmatites correspond to H 2 O-CO 2 low salinity fluids, composition of which evolved from 20 to 23 to <5 mol% CO 2 , and from 2 to 4-6 mol% NaCl eq. Sudden decrease in the CO 2 content of the post-magmatic fluids (<5 mol% CO 2 ) seems to coincide with the enrichment of the fluid in calcium (from the contamination process) and resulted in precipitation of calcites (frequently found as trapped solid phases in fluid inclusions). The fluids associated with lithium pegmatites are more complex (H 2 O-CO 2 /N 2 -H 3 BO 3 -NaCl). The CO 2 content of early exsolved fluid is 26-20 mol% CO 2 and remains the same in the next fluid generation. The main difference between the magmatic and the first post-magmatic fluids is the presence of 7-9 wt% of H 3 BO 3 (identified as daughter mineral sassolite) in the former. The second post-magmatic fluids are again CO 2 -poor (~4 mol%) and more saline (~4 mol% NaCl eq.). The composition of exsolved fluid was further used to constrain volatile composition and content of the parental melts. Finally, P-T conditions of pegmatite crystallization are constrained: 600-640°C and 420-580 MPa for the barren pegmatites and 500-570°C and 310-430 MPa for the lithium pegmatite. While the emplacement of the former occurred in thermal equilibrium with the Moldanubian host rock environment, the emplacement of the later suggests substantial thermal disequilibrium.

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Skarns in the Svratka Unit, in the neighbouring part of the Moldanubian Zone and in the Kutná Hora Complex were studied with respect to their metamorphic evolution, major-and trace-element geochemistry, oxygen isotopic composition and zircon ages. Skarns form competent lenses and layers in metamorphosed siliciclastic rocks and preserve some early deformation structures and several equilibrium assemblages representing the products of successive metamorphic reactions. The main rock-forming minerals, garnet and clinopyroxene, are accompanied by less abundant magnetite, amphibole, plagioclase, epidote ± quartz. In the Svratka Unit the early prograde M 1 , prograde/peak M 2 , and retrograde M 3 metamorphic stages have been distinguished. Metamorphic conditions in skarns of the Moldanubian Zone are limited to a relatively narrow interval of amphibolite facies. The prograde and retrograde events in the Kutná Hora Complex skarns probably took place under amphibolite-facies conditions. The presence of magnetite and the increasing proportion of the andradite component in the garnet indicate locally increased oxygen fugacity. Skarn geochemistry does not show systematic differences in the skarn composition among the three units. The regional variations are exceeded by differences among samples from individual localities. The Al 2 O 3 /TiO 2 , Al 2 O 3 /Zr, TiO 2 /Nb ratios point to the variable proportion of the detrital material, combined in skarn protoliths with CaO and FeO, the major non-detrital components. The skarns exhibit elevated abundances of Cu, Zn, Sn and As. The Eu/Eu* ratio varies in the range of 0.5-8.6, the total REE contents vary from 8 to 345 ppm. The lowest ΣREE values (< 100 ppm) occur in skarns with magnetite mineralization. The wide intervals of ΣREE and Eu/Eu* values are interpreted to indicate variations in the temperature and redox conditions among layers of the same locality and at various localities. The oxygen isotope compositions of garnets, pyroxenes and amphiboles from skarns of the Svratka Unit exhibit a range of δ 18 O = 0.1 to 4.1 ‰. In situ (laser-ablation ICP-MS) U-Pb dating of zircon from one of the Svratka Unit skarn bodies yielded a wide range of ages (0.5-2.6 Ga), supporting the detrital origin of this zircon population. The skarn protoliths were probably rocks of mixed detrital-exhalative origin deposited on the sea floor. The geological position of skarns, with their structural and metamorphic record, probably reflect tectono-metamorphic evolution shared with that of their host rocks. The geochemical characteristics, including oxygen isotopic compositions and the presence of detrital zircons with a wide range of ages exclude metasomatic, and point to a sedimentary-exhalative mode of origin for the studied skarns.