No abstract

During the second phase of the Alpine Fault, Deep Fault Drilling Project (DFDP) in the Whataroa River, South Westland, New Zealand, bedrock was encountered in the DFDP-2B borehole from 238.5-893.2 m Measured Depth (MD). Continuous sampling and meso-to microscale characterization of whole rock cuttings established that, in sequence, the borehole sampled amphibolite facies, Torlesse Composite Terrane-derived schists, protomylonites, and mylonites, terminating 200-400 m above an Alpine Fault Principal Slip Zone (PSZ) with a maximum dip of 62°. The most diagnostic structural features of increasing PSZ proximity were the occurrence of shear bands and reduction in mean quartz grain sizes. A change in composition to greater mica:quartz+feldspar, most markedly below ~ 700 m MD, is inferred to result from either heterogeneous sampling or a change in lithology related to alteration. Major oxide variations suggest the fault-proximal Alpine Fault alteration zone, as previously defined in DFDP-1 core, was not sampled.

Fault rock assemblages reflect interaction between deformation, stress, temperature, fluid, and chemical regimes on distinct spatial and temporal scales at various positions in the crust. Here we interpret measurements made in the hanging‐wall of the Alpine Fault during the second stage of the Deep Fault Drilling Project (DFDP‐2). We present observational evidence for extensive fracturing and high hanging‐wall hydraulic conductivity (∼10−9 to 10−7 m/s, corresponding to permeability of ∼10−16 to 10−14 m2) extending several hundred meters from the fault's principal slip zone. Mud losses, gas chemistry anomalies, and petrophysical data indicate that a subset of fractures intersected by the borehole are capable of transmitting fluid volumes of several cubic meters on time scales of hours. DFDP‐2 observations and other data suggest that this hydrogeologically active portion of the fault zone in the hanging‐wall is several kilometers wide in the uppermost crust. This finding is consistent with numerical models of earthquake rupture and off‐fault damage. We conclude that the mechanically and hydrogeologically active part of the Alpine Fault is a more dynamic and extensive feature than commonly described in models based on exhumed faults. We propose that the hydrogeologically active damage zone of the Alpine Fault and other large active faults in areas of high topographic relief can be subdivided into an inner zone in which damage is controlled principally by earthquake rupture processes and an outer zone in which damage reflects coseismic shaking, strain accumulation and release on interseismic timescales, and inherited fracturing related to exhumation.

Abstract. Graphitization, or the progressive maturation of carbonaceous material, is considered an irreversible process. Thus, the degree of graphite crystallinity, or its structural order, has been calibrated as an indicator of the peak metamorphic temperatures experienced by the host rocks. However, discrepancies between temperatures indicated by graphite crystallinity versus other thermometers have been documented in deformed rocks. To examine the possibility of mechanical modifications of graphite structure and the potential impacts on graphite thermometry, we performed laboratory deformation experiments. We sheared highly crystalline graphite powder at normal stresses of 5 and 25  megapascal (MPa) and aseismic velocities of 1, 10 and 100 µm s−1. The degree of structural order both in the starting and resulting materials was analyzed by Raman microspectroscopy. Our results demonstrate structural disorder of graphite, manifested as changes in the Raman spectra. Microstructural observations show that brittle processes caused the documented mechanical modifications of the aggregate graphite crystallinity. We conclude that the calibrated graphite thermometer is ambiguous in active tectonic settings.

Graphitisation in fault zones is associated both with fault weakening and orogenic gold mineralisation. We examine processes of graphite emplacement and deformation in the Alpine Textural changes of graphite 2 Fault Zone, New Zealand's active continental tectonic plate boundary. Optical and scanning electron microscopic observations reveal a microstructural record of mobilisation of graphite as a function of temperature and ductile then brittle shear strain. Raman spectrometry allowed interpretation of the degree of maturity of carbonaceous material (CM), which reflects thermal and mechanical processes. In the amphibolite-facies Alpine Schist highly crystalline graphite, indicating peak metamorphic temperatures up to 640 • C, occurs mainly on grain boundaries within quartzo-feldspathic domains. The subsequent mylonitization process resulted in reworking of CM under lower temperature conditions (500 • C-600 • C) in a structurally controlled environment, resulting in clustered (in protomylonites) and foliation aligned CM (in true mylonites). In the brittlely-deformed rocks (cataclasites derived from the mylonitised schists) graphite is most abundant (<50%) and has two different habits: inherited mylonitic graphite and less mature patches of potentially hydrothermal graphite. Tectonic-hydrothermal fluid flow was probably important in deposition of graphite throughout the examined rock sequences. The increasing abundance of graphite may be a significant source of fault weakening, allowing strain localisation, as the fault rocks are progressively exhumed.