Thermochemical multistep water- and CO2-splitting processes are promising options to face future energy problems. Particularly, the possible incorporation of solar power makes these processes sustainable and environmentally attractive since only water, CO2 and solar power are used; the concentrated solar energy is converted into storable and transportable fuels. One of the major barriers to technological success is the identification of suitable active materials like catalysts and redox materials exhibiting satisfactory durability, reactivity and efficiencies. Moreover, materials play an important role in the construction of key components and for the implementation in commercial solar plants. The most promising thermochemical water- and CO2-splitting processes are being described and discussed with respect to further development and future potential. The main materials-related challenges of those processes are being analyzed. Technical approaches and development progress in terms of solving them are addressed and assessed in this review.

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Solar radiation is the largest indigenous energy resource worldwide. It will gain a significantly more relevant role in covering the energy demand of many countries when national fuel reserves fall short and when demand increases as is expected within the next 10 years. If solar energy is transformed into heat by concentrating and absorbing the radiation, energy can be stored easily. Thermal energy from mirror fields that focus solar radiation not only is able to generate electricity but also can be used to generate storable heat, to desalinate salt water or to synthesise fuels from water and carbon dioxide to store, transport or use them on-site. The application of concentrated solar radiation as a primary energy source can help to decarbonise electricity generation and many other sectors to keep the chance of staying within the 2 C goal for limiting the effects of global warming. The aim of the present contribution is to give an overview on the state-of-the art of technologies for solar thermal power production and fuel production and to describe the status and outlook of commercial projects and perspectives of market development.