No abstract

Keywords: ab initio calculations . electrochemistry . lanthanide compounds [l] For a recent review on metallofullerenes. see:

The synthesis, structural, and theoretical characterization of heterobimetallic complexes [CH3Si{SiMe2N(4-CH3C6H4)}3M−Co(CO)3(L)] (M = Ti, Zr; L = CO, PPh3, PTol3) with unsupported metal−metal bonds between cobalt atoms and titanium or zirconium atoms is being reported. The synthesis of the dinuclear compounds was achieved by salt metathesis of the chlorotitanium and zirconium complexes and the alkalimetal carbonylates. X-ray crystal structure analyses of four of these heterobimetallic complexes established the unsupported metal−metal bonds [M = Ti, L = CO (3):  2.554(1) Å; M = Ti, L = PTol3 (4b):  2.473(4) Å; M = Zr, L = CO (5):  2.705(1) Å; M = Zr, L = PPh3 (6a):  2.617(1) Å] as well as the 3-fold molecular symmetries. Upon axial phosphine substitution, a metal−metal bond contraction of ca. 0.08 Å is observed, which also results in the quantum chemical structure optimizations performed on the model compounds [(H2N)3Ti−Co(CO)4] (3x) and [(H2N)3Ti−Co(CO)3(PH3)] (4x) using gradient-corrected and hybrid density functionals. A theoretical study of the homolytic dissociation of the metal−metal bonds focuses on the relaxation energies of the complex fragments and indicates that the geometrical constraints imposed by the tripod ligand lead to a major thermodynamic contribution to the stability of the experimentally investigated complexes. The central question of the polarity of the metal−metal bond is addressed by detailed analysis of the calculated electron charge distribution using natural population analysis (NPA), charge decomposition analysis (CDA), Bader's atoms in molecules (AIM) theory, and the electron localization function (ELF). Both the orbital-based NPA and CDA schemes and the essentially orbital-independent AIM and ELF analysis suggest a description of the Ti−Co bond as being a highly polar covalent single bond. The combination of AIM and ELF is employed for the first time to analyze metal−metal bond polarity and appears to be a powerful theoretical tool for the description of bond polarity in potentially ambiguous situations.

The novel tridentate diamidoamine ligands [RC(2-C5H4N)(CH2NSiMe,),l2~ (R = H, CH3) have been synthesized and coordinated to TiIV and ZrIV giving the pentacoordi- [~] have been studied in most detail. While they have enabled the stabilization of otherwise elusive molecular stuctures and offered the possiblity to investigate their reactivity, the scope of their use is limited. This warrants continuing efforts in the area of ligand design[9' and, given the results of the approach mentioned above, polyfunctional derivatives of amido systems are attractive candidates when early transition metals are involved.Our research has focussed on the metals of the titanium triad and the trianionic tripodal aniido ligands employed have generated nionofunctional MIv complexes, i.e. compounds in which one anionic ligand (such as a halide) may be substituted to yield derivatives. In order to study the chemistry of d

The 1+1 reaction of the symmetrical dimers [ClP(m-N t Bu)] 2 1 and [H 2 NP(m-N t Bu)] 2 2 in thf-Et 3 N gives the tetrameric macrocycle [{P(m-N t Bu)} 2 NH] 4 3 (67%); consisting of four P 2 (m-N t Bu) 2 rings linked by endo N-H groups.