phosphonate-based bimetallic metal-organic frameworks, namely STA-12(M 1 , M 2 ) (M 1 , M 2 = Mn, Fe, Co), show photocatalytic activity for the degradation of Rhodamine B (RhB) and Methylene blue (MB) from aqueous solution under natural sunlight irradiation. The degradation of the dyes, appears to be faster with STA-12(Fe, Mn) than other synthesized MOFs. Thus, photo-Fenton oxidative discoloration of dyes has been studied by H 2 O 2 catalyzed with the STA-12(Fe, Mn). The process is first order with respect to dyes and the synergistic index in the STA-12(Fe, Mn)/sunlight/H 2 O 2 system reached as high as 472%.Mineralization of dyes was discussed by spectroscopic and TOC measurement. Besides, the efficiency of STA-12(Fe, Mn) used in photocatalytic process was attentively investigated through the characterization of reactive radicals, the stability and reusability of the photocatalyst, also the effect of operational parameters such as H 2 O 2 dosage, solution pH and initial dye concentration.This work demonstrates the first example of facilitating photo-Fenton-like excitation of H 2 O 2 via phosphonate based mixed metal organic frameworks as photocatalysts and explained a new opportunity for solar-induced AOP environmental remediation and protection.
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