A purpose of the research was to develop a method for the preparation of novel organo-mineral fertilizers with the use of brown coal and biochars as organic additives. Brown coal was blended simultaneously together with inorganic materials used for the process of urea superphosphate production in a laboratory scale using a pan granulator and in larger scale using a rapid mixer granulator. Biochars were used for the coating purposes of the urea superphosphate granules on a laboratory scale using a pan granulator. Moreover, the aim was to measure and evaluate the physico-chemical properties of organic materials and the obtained organo-mineral fertilizer products and to study the effects of these products on the selected yield components of spring wheat such as grain yield per plant, spike number per plant, and plant height, in pot trials. Results showed that brown coal and biochars can be used as raw materials for production of fertilizer products. Brown coal contained about 50% of total humic acids while biochar contained nearly 6% of total humic-like substances. Brown coal based compound fertilizer granules produced in the large scale were characterized by particle hardness from 15.80 to 23.3 N while those produced in the laboratory scale were classified as "soft" (particle hardness below 2.3 N). The application of brown coal based fertilizers and two studied biochar coated fertilizers had a positive impact on the grain yield per plant of spring wheat.

The purpose of this research was to determine and evaluate the chemical properties of drilling waste from five well sites in Central and Eastern Poland. It was found that spent drilling fluids can contain high values of nickel and mercury (270 and 8.77 mg kg respectively) and can exceed the maximum permissible limits recommended by the EC regulations for safety of soils (75 mg kg for nickel and 1.5 mg kg for mercury). The heavy metal concentrations in the studied drill cuttings did not exceed the maximum permissible limits recommended by the EC regulation. Drilling wastes contain macroelements (e.g., calcium, magnesium, and potassium) as well as trace elements (e.g., copper, iron, zinc, and manganese) that are essential for the plant growth. It was stated that water extracts of drilling fluids and drill cuttings, according to anions presence, had not any specific constituents of concern based on FAO irrigation guidelines, the USEPA WQC, and toxicity values. X-ray diffraction analysis was used to understand the structure and texture of waste drilling fluid solids and drill cuttings. Analysis of the mineralogical character of drilling fluid solids revealed that they contained calcite, quartz, muscovite, sylvite, barite, dolomite, and orthoclase. Drill cuttings contained calcite quartz, muscovite, barite, dolomite, and barium chloride.

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The present research was carried out to investigate the effects of different fertilizer treatments on grain yield and yield components of spring wheat (Triticum aestivum L.) 'Harenda' cultivar. The five treatments were as follows: control (standard NPK fertilization), standard NPK fertilization plus liquid NPK (10-11-11) fertilizer, standard NPK fertilization plus liquid NPK (10-11-11) fertilizer with microelements, standard NPK fertilization plus calcium micronized suspension fertilizer, and standard NPK fertilization plus Cu, Mn, Zn, Ca micronized suspension fertilizers. The field trials were conducted in 2017 at the Experimental Site of Institute of Soil Science and Plant Cultivation-State Research Institute in Puławy, Poland. Applications of calcium micronized suspension foliar fertilizer and a mixture of Cu, Mn, Zn, Ca micronized suspension fertilizers significantly increased grain yield of spring wheat, respectively by 44.5% and 38.6% in comparison with control (standard NPK fertilization). These fertilizer treatments also enhanced yield components of spring wheat. Moreover, micronized suspension fertilizers (Ca and the mixture of Cu, Mn, Zn, Ca) had a significant effect on ear number and thousand grain weight of spring wheat compared to control and NPK fertilizers. Liquid NPK and micronutrient-enriched NPK fertilizers had a significant effect on thousand grain weight compared to control.