Experiments were conducted to investigate two-phase flow instabilities in a boiling natural circulation loop with a chimney at high pressure. The SIRIUS-N facility was designed to have non-dimensional values which are nearly equal to those of a typical natural circulation BWR. The observed oscillations are found to be density wave oscillations, since the void fractions in the chimney inlet and exit are out of phase. They belong to the Type-I category, since they occur at low flow qualities, according to the Fukuda-Kobori's classification. Moreover, the oscillation period correlates well with the passing time of bubbles in the chimney section regardless of the system pressure, the heat flux, and the inlet subcooling. Two distinct phenomena are found in relation between the oscillation period and liquid passing time in the chimney, indicating that the driving mechanisms of the instabilities are different between low and high pressures. Stability maps were obtained in reference to the inlet subcooling and the heat flux at the system pressures of 1, 2, 4, and 7.2 MPa. The flow became stable below a certain heat flux regardless of the channel inlet subcooling. The stable region enlarges with increasing system pressure. Thus, the stability margin becomes larger in a startup process of a reactor by pressurizing the reactor sufficiently before withdrawing the control rods. The obtained stability map demonstrates that the nominal operating condition of the ESBWR has a significant stability margin to the unstable region.
When a metal oxide is irradiated by gamma rays, the irradiated surface becomes hydrophilic. This surface phenomenon is called as radiation-induced surface activation (RISA) hydrophilicity. In order to investigate gamma ray-induced and photoinduced hydrophilicity, the contact angles of water droplets on a titanium dioxide surface were measured in terms of irradiation intensity and time for gamma rays of cobalt-60 and for ultraviolet rays. Reciprocals of the contact angles increased in proportion to the irradiation time before the contact angles reached its super-hydrophilic state. The irradiation time dependency is equal to each other qualitatively. In addition, an effect of ambient gas was investigated. In pure argon gas, the contact angle remains the same against the irradiation time. This clearly indicates that certain humidity is required in ambient gas to take place of RISA hydrophilicity. A single crystal titanium dioxide (100) surface was analyzed by X-ray photoelectron spectrometry (XPS). After irradiation with gamma rays, a peak was found in the O1s spectrum, which indicates the adsorption of dissociative water to a surface 5-fold coordinate titanium site, and the formation of a surface hydroxyl group. We conclude that the RISA hydrophilicity is caused by chemisorption of the hydroxyl group on the surface.
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