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The first-ever use of halloysite nanotube (HNT), a relatively low-cost nanomaterial abundantly available with minor toxicity for removing brilliant green dye from aqueous media, is reported. The factors affecting adsorption were studied by assessing the adsorption capacity, kinetics, and equilibrium thermodynamic properties. All the experiments were designed at a pH level of around 7. The Redlich-Peterson isotherm model fits best amongst the nine isotherm models studied. The kinetic studies data confirmed a pseudo model of the second order. Robotic investigations propose a rate-controlling advance being overwhelmed by intraparticle dispersion. The adsorbent features were interpreted using infrared spectroscopy and electron microscopy. Process optimization was carried out using Response Surface Methodology (RSM) through a dual section Fractional Factorial Experimental Design to contemplate the impact of boundaries on the course of adsorption. The examination of fluctuation (ANOVA) was utilized to consider the joined impact of the boundaries. The possibilities of the use of dye adsorbing HNT (“sludge”) for the fabrication of the composites using plastic waste are suggested.

Bio-char has the ability to isolate carbon in soils and concurrently improve plant growth and soil quality, high energy density and also it can be used as an adsorbent for water treatment. In the current work, the characteristics of four different types of bio-chars, obtained from slow pyrolysis at 375 °C, produced from hard-, medium-, thin- and paper-shelled walnut residues have been studied. Bio-char properties such as proximate, ultimate analysis, heating values, surface area, pH values, thermal degradation behavior, morphological and crystalline nature and functional characterization using FTIR were determined. The pyrolytic behavior of bio-char is studied using thermogravimetric analysis (TGA) in an oxidizing atmosphere. SEM analysis confirmed morphological change and showed heterogeneous and rough texture structure. Crystalline nature of the bio-chars is established by X-ray powder diffraction (XRD) analysis. The maximum higher heating values (HHV), high fixed carbon content and surface area obtained for walnut shells (WS) samples are found as ~ 18.4 MJ kg−1, >80% and 58 m2/g, respectively. Improvement in HHV and decrease of O/C and H/C ratios lead the bio-char samples to fall into the category of coal and confirmed their hydrophobic, carbonized and aromatized nature. From the Fourier transform infra-red spectroscopy (FTIR), it is observed that there is alteration in functional groups with increase in temperature, and illustrated higher aromaticity. This showed that bio-chars have high potential to be used as solid fuel either for direct combustion or for thermal conversion processes in boilers, kilns and furnace. Further, from surface area and pH analysis of bio-chars, it is found that WS bio-chars have similar characteristics of adsorbents used for water purifications, retention of essential elements in soil and carbon sequestration.