Photodetection in the short-wave infrared (SWIR) spectrum is a challenging task achieved often by costly low bandgap compound semiconductors involving highly toxic elements. In this work, an alternative low-cost approach is reported for SWIR sensors that rely on the plasmonic-induced photothermal effect of solution-processed colloidal gold nanorods (Au NRs). A series of uniform solution-processed Au NRs of various aspect ratios are prepared exhibiting a strong and well-defined longitudinal localized surface plasmon resonance (L-LSPR) maximum from 900 nm to 1.3 µm. A hybrid device structure is fabricated by applying Au NRs on the surface of a thermistor. Under a monochromatic illumination, hybrid Au-NR/thermistor devices exhibit a clear photoresponse in the form of photoinduced resistance drop in the wavelength window from 1.0 to 1.8 µm. The photoresponsivity of such hybrid devices reaches a maximum value of 4.44 × 10 Ω W at λ = 1.4 µm (intensity = 0.28 mW cm ), a wavelength in agreement with the L-LSPR of the Au NRs applied. Colloidal Au NRs, capable to perform fast conversion between photon absorption and thermal energy, thus open an interesting avenue for alternative low-cost SWIR photodetection.

Photon upconversion represents a promising avenue to reduce the spectral mismatch losses limiting the efficiency of solar cells. Here we studied in detail the impact of inserting Yb 3+ /Er 3+ codoped KY 7 F 22 upconversion nanoparticles (UCNPs) into the different interfaces of a solution-processed mixed-cation lead mixedhalide perovskite solar cell. Besides macroscopic photovoltaic characteristics, we quantify the upconversion contribution by the light-beam-induced current/fluorescence mapping technique on devices with only half of their interfaces decorated by UCNPs. Such mapping experiments offer a detailed microscopic and spectroscopic picture allowing a correlation of the electrical and optical contribution of UCNPs together with the solar cell morphology.