No abstract

After heating the acetone under the porous [OMIM][BF4] to 120 K, the acetone diffuses into pores lined with octyl chains (destabilised acetone) and pores lined with ions (stabilised acetone).

Variable period X-ray standing wave (VPXSW) studies have been carried out using 3 keV X-rays and photoelectron detection. Two model surfaces have been used, a native SiO 2 layer (20 Å thick) on bulk silicon, and a purpose built multilayer surface comprising a chloroform/water marker layer (12 Å thick) on an ionic liquid spacer layer (211 Å thick) deposited on a SiO 2 /Si substrate at 90 K. By using photoelectron detection, both chemical and elemental sensitivity were achieved. The surfaces were modelled using dynamic X-ray scattering for X-ray intensity, and attenuation of photoelectrons transmitted through the layers, to produce simulations which accurately reproduced the experimental VPXSW measurements. VPXSW measurements made using the substrate, spacer layer and marker layer photoelectron signatures produced consistent structural values. This work demonstrates that VPXSW can be used to determine chemically specific layer thicknesses within thick (≲ 300 Å) surface structures composed of the light elements B, C, N, O, F and Cl with an accuracy of 10 to 15 Å, perpendicular to the surface.