We explore collisions of hydrogen-bonding molecules with salty water using gas–microjet scattering experiments. Two aqueous solutions, 8 molal (m) LiBr/H2O and ∼4 m K2SO3/H2O at 253 K were exposed to seven organic gases representing different functional groups. These gases comprise weak acids (formic and acetic), weak bases (dimethylamine and piperidine), and an alcohol, ether, and ester (ethanol, dimethyl ether, and methyl formate). The scattering experiments are used to monitor the disappearance of each gas into the aqueous solutions over a ∼100 μs observation time. They demonstrate that formic acid and piperidine disappear into both solutions on almost every collision. Dimers of formic and acetic acid are also captured by the solutions on every collision, despite their pre-existing double hydrogen bonds. The methylene ring of piperidine, (CH2)5NH, also does not interfere with uptake. At the opposite extreme, methyl formate and dimethyl ether are so weakly soluble that they evaporate completely within the observation window, precluding the measurement of their entry probability. Ethanol and dimethylamine represent intermediate cases in which dimethylamine interacts more strongly with dissolved Li+ ions than K+ ions. Collectively, the experiments imply that organic acids and bases reach hydrogen-bonding configurations following nearly every collision, enabling them to be captured by surface water molecules.
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