Speeds of sound have been measured in ethyl myristate (C 16 H 32 O 2 ), methyl myristate (C 15 H 30 O 2 ), and methyl palmitate (C 17 H 34 O 2 ) at pressures up to 100 MPa along isotherms ranging from (293.15 to 403.15) K. The measurements were carried out using a pulse echo technique operating at 3 MHz. Additional compressed liquid density measurements were performed from (293.15 to 393.15) K with pressures from (0.1 to 100) MPa in order to evaluate isentropic compressibility using speed of sound measurements. An equation of state that represents both the density and the speed of sound temperature reported experimental data within their estimated uncertainties is given to evaluate the volume as well as its derivatives of these components.
International audienceThe paper reports high pressure data of the viscosity of methyl caprate (C11H22O2) and ethyl caprate (C12H24O2). The measurements cover the temperature range from (293.15 to 353.15) K, from atmospheric pressure up to 200 MPa and were carried out by two different methods. One is based on a falling-body viscometer, whereas the other rests on a quartz crystal resonator technique. Based on the two sets of data, high pressure viscosity correlations are proposed to correlate within the experimental uncertainty the viscosity values as a function of temperature and pressure. Finally, a thermodynamic scaling method was used to describe the viscosity in terms of density and temperature
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