We explore the influence of major elements chemistry and H 2 O-content on the density and seismic velocity of crustal rocks by computing stable and metastable crustal mineralogy and elastic properties as a function of pressure and temperature (P-T). Proposed average compositions of continental crust result in significantly different properties, for example a difference in computed density of $ 4 % is obtained at a given P-T. Phase transformations affect crustal properties at the point that crustal seismic discontinuities can be explained with mineral reactions rather than chemical stratification. H 2 O, even if introduced in small amount in the chemical system, has an effect on physical properties comparable to that attributed to variations in major elements composition. Thermodynamical relationships between physical properties differ significantly from commonly used empirical relationships. Density models obtained by inverting CRUST 1.0 compressional wave velocity are different from CRUST 1.0 density and translate into variations in isostatic topography and gravitational field that ranges 6600 m and 6150 mGal respectively. Inferred temperatures are higher than reference geotherms in the upper crust and in the deeper portions of thick orogenic crust, consistently with presence of metastable rocks. Our results highlight interconnections/dependencies among chemistry, pressure, temperature, seismic velocities and density that need to be addressed to better understand the crustal thermo-chemical state.

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In this work, we study the lithospheric structure of the British Isles using a methodology that allows for forward modeling of the Curie temperature depth based on seismic, elevation and gravity observations within an integrated geophysical-petrological approach (LitMod3D). We compute 3D thermal models and self-consistently determine the density in the mantle based on temperature, pressure, and bulk composition. Finally, we derive Curie temperature depth maps and forward calculate magnetic anomalies at the airborne level (5 km altitude) using a spherical magnetic modeling software (magnetic tesseroids) to estimate the geothermal magnetic signal. Our results show lateral lithospheric variations across the model domain, with Great Britain being characterized in general by thicker and colder lithosphere, especially in the south-east, and the thinnest and warmest lithosphere being located beneath west Scotland, Northern Ireland and in the north-west oceanic area. Our estimated Curie temperature depth map resembles the values obtained using other techniques (spectral method and surface heat flow inversion) in some areas, but discrepancies are notable in general. We determine that the effect of typical lateral temperature variations (i.e., Curie isotherm depth) accounts for 5-15%, on average, and up to 70% locally of the crustal magnetic signal at the airborne level. Our lithospheric models are in general agreement with published seismic tomography models as well as other geophysical studies.

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