Static
dissipater additives (SDAs) are conductivity improver additives
that are added to aviation turbine fuels (ATFs) to avoid sudden increase
in conductivity that may occur during transfer/pumping of ATF. STADIS
450 has been used globally as the SDA in aviation jet A1. The dosage
of SDA into jet fuels is very closely specified (1–3 ppm).
Due to surface active nature, SDA dosage may deplete with time. The
monitoring of concentration of SDA is very critical and is generally
carried out using conductivity measurement as per ASTM D2624 or as
per liquid chromatographic technique based ASTM D7524 method entitled in “Determination of static dissipater additive
(SDA) in aviation turbine fuel using HPLC technique with UV detector
in the range of 1 to 12 ppm”. In this work, SDA blended ATFs
in the range of 1–5 ppm have been analyzed for estimation of
SDAs using both HPLC based ASTM D7524 and conductivity measurement
based ASTM D2624. This paper suggests precautions that need to be
taken while using the two methods. The work also recommends suggestions
that can make the ASTM D7524 findings more specific and precise and
ensures better recoveries. While the initial procedures were adopted
from ASTM D7524, multiple collections during cartridge extraction
process and use of HPLC with photodiode detector instead of UV detector
bring down the detection level to 0.5 ppm of SDA in ATF.
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