This paper describes work to study oxidation and hot corrosion damage in nickel disc alloy RR1000. Oxidation damage has been characterised via mass change data from thermogravimetric analyses at temperatures from 700 to 800 ºC and cyclic oxidation testing at 700 and 750 ºC. Thin oxide scales rich in Cr and Ti have been found to grow in a parabolic dependence with time. Oxidation rate constants have been correlated with temperature using an Arrhenius equation. Through the use of simplifying assumptions, mass change data have been converted to oxide thickness values. These values have been compared with observed values of oxide scale and the depth of near-surface damage, which have been measured using focused ion beam (FIB) microscopy.Hot corrosion of RR1000 has been studied in the laboratory by 'deposit' recoat experiments at 700ºC. In these tests, samples were coated with deposits of Na 2 SO 4 /NaCl salt in a gas stream of air-300 vpm SO 2 . Corrosion damage has been quantified by dimensional metrology of samples before and after exposure. This enabled metal losses, i.e. the depth of corrosion pits, to be determined. Distributions of metal loss data were then generated to produce median damage values and exceedance cumulative probabilities. Finally, the effect of contaminants on the hot corrosion resistance of RR1000 has also been evaluated.
The development of an affordable nickel disc alloy that shows the required combination of strength, damage tolerance and creep resistance continues to challenge materials engineers. RollsRoyce has developed the alloy known as RR1000, which when processed to produce a fine grain microstructure, shows at least a 25ºC increase in temperature capability over the current disc alloy, 720Li, and has an equivalent crack growth resistance to coarse grain Waspaloy. This paper discusses the steps that were taken to attain these mechanical properties, and also examines the potential to increase temperature capability by a further 30ºC through the development of a coarse microstructure in selected areas of disc forgings.
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