Pre-irradiation method was applied to graft acrylonitrile (AN) onto non-woven polyethylene film. Graft yield reached 130% at 70 kGy radiation dose, 60% monomer concentration and 4 h reaction time when H 2 SO 4 was used as an additive. The modification of AN grafted films with hydroxyl amine hydrochloride was done for the preparation of amidoxime adsorbent. The constructed adsorbent was characterized using FTIR, DMA and SEM. The amidoxime adsorbent was used for adsorption of Cu(II), Pb(II) and Cr(VI). Adsorption capacity was investigated under different conditions: contact time, pH and initial metal ion concentration. The optimum condition for maximum adsorption was found to be contact time 72 h and initial metal concentration 500 ppm for all the metal ions studied and pH 5.2 for Cu(II), 5.4 for Pb(II), 1.5 for Cr(VI). Kinetic adsorption data was elucidated using pseudo-first-order and pseudo-second-order equations. The equilibrium experimental data of metal adsorption matched Langmuir isotherm model. From the Langmuir equation, the monolayer saturation adsorption capacity (highest adsorption capacity) of the adsorbent was found to be 74.62 mg/g for Cu(II), 107 mg/g for Pb(II) and 156.25 mg/g for Cr(VI). The thermodynamics of metal adsorption was also investigated. Furthermore, desorption and reuse of the adsorbent film was studied. The results suggest that the adsorbent can be effective for adsorption of Cu(II), Pb(II) and Cr(VI).

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The secrecy performance of realistic wireless multicast scenarios can be significantly deteriorated by the simultaneous occurrence of multipath and shadowing. To resolve this security threat, in this work an opportunistic relaying-based dual-hop wireless multicast framework is proposed in which the source dispatches confidential information to a bunch of receivers via intermediate relays under the wiretapping attempts of multiple eavesdroppers. Two scenarios, i.e. non-line of sight (NLOS) and line of sight (LOS) communications along with the multiplicative and LOS shadowing are considered where the first scenario assumes η − µ and η − µ/inverse Gamma (IG) composite fading channels and the latter one follows κ − µ and κ − µ/IG composite fading channels as the source to relay and relay to receiver's as well as eavesdropper's links, respectively. Secrecy analysis is accomplished by deriving closed-form expressions of three familiar secrecy measures i.e. secure outage probability for multicasting, probability of non-zero secrecy multicast capacity, and ergodic secrecy multicast capacity. We further capitalize on those expressions to observe the effects of all system parameters which are again corroborated via Monte-Carlo simulations.Our observations indicate that a secrecy tradeoff between the number of relays and number of receivers, eavesdroppers, and shadowing parameters can be established to maintain the admissible security level by decreasing the detrimental influences of fading, shadowing, the number of multicast receivers and eavesdroppers.