a b s t r a c tZnO nanoparticles have been synthesized by the sol-gel method with approximately 10 nm diameter and the humidity adsorption and desorption kinetics of ZnO nanoparticles were investigated by quartz crystal microbalance (QCM) technique. The morphology and crystal structure of the ZnO nanoparticles have been characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD), respectively. The roughness of the surface has been investigated using atomic force microscope (AFM). The dynamic Langmuir adsorption model was used to determine the kinetic parameters such as adsorption and desorption rates and Gibbs free energy under relative humidity between 45% and 88%. The relative sensitivity of the ZnO nanoparticles-based humidity sensor was determined by electrical resistance measurements. Our reproducible experimental results show that ZnO nanoparticles have a great potential for humidity sensing applications at room temperature operations.
Neuroimaging techniques are widely used in neuroscience to visualize neural activity, to improve our understanding of brain mechanisms, and to identify biomarkers-especially for psychiatric diseases; however, each neuroimaging technique has several limitations. These limitations led to the development of multimodal neuroimaging (MN), which combines data obtained from multiple neuroimaging techniques, such as electroencephalography, functional magnetic resonance imaging, and yields more detailed information about brain dynamics. There are several types of MN, including visual inspection, data integration, and data fusion. This literature review aimed to provide a brief summary and basic information about MN techniques (data fusion approaches in particular) and classification approaches. Data fusion approaches are generally categorized as asymmetric and symmetric. The present review focused exclusively on studies based on symmetric data fusion methods (data-driven methods), such as independent component analysis and principal component analysis. Machine learning techniques have recently been introduced for use in identifying diseases and biomarkers of disease. The machine learning technique most widely used by neuroscientists is classification-especially support vector machine classification. Several studies differentiated patients with psychiatric diseases and healthy controls with using combined datasets. The common conclusion among these studies is that the prediction of diseases increases when combining data via MN techniques; however, there remain a few challenges associated with MN, such as sample size. Perhaps in the future N-way fusion can be used to combine multiple neuroimaging techniques or nonimaging predictors (eg, cognitive ability) to overcome the limitations of MN.
a b s t r a c tThe humidity-sensing properties of ZnO nanowires synthesized by carbothermal catalyst-free vapor solid (VS) technique were studied. The morphology and the crystal structure were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD), respectively. The humidity adsorption and desorption kinetics of the synthesized ZnO nanowires were investigated via quartz crystal microbalance (QCM) measurements. The observed positive frequency shift of ZnO nanowires when loaded on the QCM crystal under varying relative humidity conditions can be explained in terms of visco-elastic variations in their mechanical stiffness.
We present a comprehensive study of longitudinal transport of two-dimensional (2D) carriers in n- and p-type modulation doped Ga(x)In(1-x)N(y)As(1-y) /GaAs quantum well structures. The Hall mobility and carrier density of electrons in the n-modulation doped quantum wells (QWs) decreases with increasing nitrogen composition. However, the mobility of the 2D holes in p-modulation doped wells is not influenced by nitrogen and it is significantly higher than that of 2D electrons in n-modulation doped material. The observed behaviour is explained in terms of increasing electron effective mass as well as enhanced N-related alloying scattering with increasing nitrogen content. In order to determine the conduction band (CB) and valence band (VB) structures as well as electron and hole effective masses, the band anticrossing model with an eight-band [Formula: see text] approximation in the Lüttinger-Kohn approach is used. The effects of strain, quantum confinement and the strong coupling between the localized nitrogen states and the CB extended states of GaInAs are considered in the calculations. The results indicate that the nitrogen induces a strong perturbation to the CB of the matrix semiconductor whilst the VB remains unaffected. The temperature dependent mobility of 2D electron gas is discussed using an analytical model that accounts for the most important scattering mechanisms. The results indicate that the interface roughness and N-related alloy scattering are the dominant mechanisms at low temperatures, while polar optical phonon and N-related alloy scattering limit mobility at high temperatures.
In this study, molecular beam epitaxial-grown GaAs/GaBiAs single quantum well systems with two different Bi contents were investigated. Spectral dependence of room temperature photomodulated reflectance (PR) and photoluminescence (PL) measurements in the temperature range of 35-300 K were employed. PR spectra indicate that increasing Bi concentration promotes a tendency to approach quantized higher energy levels in the heavy and light holes' bands due to the different effects of compressive strain, which depends on Bi concentrations. In addition, a defect level is identified at 0.71 eV at room temperature PR spectra and is attributed to a As Ga antisite defect in GaAs barrier layers caused by the low temperature growth process. From the analysis of the temperature dependence of emission energy and amplitude in the PL spectra, localized states are determined in the range of 8 to 45 meV and attributed to the different bonding configuration of Bi clusters. Low temperature PL results imply that Bi cluster states tend to move into the valance band when Bi content increases from 2.4 to 7.0% in the GaBiAs system.
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