Mei H. Chou scite author profile

Both heterogeneous and homogeneous catalyses of water oxidation to 02 have been recently reported for metal oxides1 and aquo-or hydroxo-metal complexes.2 One of the more efficient systems involves cobalt(II) catalysis of water oxidation by Ru-(bpy)33+ (£°(Ru(bpy)33+/2+) = 1.26 V), which occurs above pH ~52a (eq 1). We have studied the kinetics and product distri-Ru(bpy)33+ + V2H20 = Ru(bpy)32+ + H++ >/402 (1)

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Mechanism of the formation of dihydrogen from the photoinduced reactions of poly(pyridine)ruthenium(II) and poly(pyridine)rhodium(III) complexes

CHAN¹,

Chou²,

Creutz³

et al. 1981

J. Am. Chem. Soc.

211

110

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Mei H. Chou

Lifetimes, spectra, and quenching of the excited states of polypyridine complexes of iron(II), ruthenium(II), and osmium(II)

Thermal and light-induced reduction of the ruthenium complex cation Ru(bpy)33+ in aqueous solution

Mechanism of the quenching of the emission of substituted polypyridineruthenium(II) complexes by iron(III), chromium(III), and europium(III) ions

Mechanisms of water oxidation to oxygen: cobalt(IV) as an intermediate in the aquocobalt(II)-catalyzed reaction

Mechanism of the formation of dihydrogen from the photoinduced reactions of poly(pyridine)ruthenium(II) and poly(pyridine)rhodium(III) complexes

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