Cyclo crosslinked polyphosphazenes (PPNs) were prepared by Hexachlorocyclotriphosphazene (HCCP) with unique P = n structure and active p-cl group and green compound phloretin. The synthesis pro cess of polyphosphazene nanospheres with Hexachlorocyclotriphosphazene as the main body and phloretin was discussed. The effects of pH value and solid-liquid ratio of solution on the adsorption of uranium by pol yphosphazene nanospheres were studied. The results show that polyphosphazene nanospheres are off white powder in appearance and spherical in microstructure. When the pH value of the solution is 4 and the solid-l iquid ratio is 0.5g ·L-1, the maximum adsorption rate of uranium is obtained.

Poly (cyclotriphosphazene-co-4,4 '- diaminodiphenylsulfone) (PZD) microspheres were synthesi zed by precipitation polymerization of Hexachlorocyclotriphosphazene (HCCP) and polyfunctional organic monomers. The products were characterized by FTIR, SEM-EDS, XPS and bet. The adsorption behavior of PZD microspheres for uranium (VI) in aqueous solution and the influence of adsorption behavior were disc ussed. The results show that the PZD microspheres have a certain adsorption capacity for uranium (VI) in a queous solution. When pH = 3.5, adsorption time is 6h, solid-liquid ratio is 2.0g • L-1 and initial concentration of uranium (VI) is 30mg • L-1, the adsorption rate of uranium reaches the maximum.