Nanocubic pyrite (FeS2) crystals with exposed (100) crystal faces and sizes of 100–200 nm were successfully synthesized via a facile hydrothermal method using greigite (Fe3S4) as the iron precursor and thiourea (NH2CSNH2) as the sulfur source. When the concentration of thiourea was 40 mmol/L, both pyrite and hematite were observed in the as-prepared sample, indicating incomplete conversion of greigite into pyrite. With an increased thiourea concentration to 80 mmol/L, pyrite was found to be the only crystalline phase in the synthesized samples. All greigite could be transformed to pyrite within 24 h via the hydrothermal method, while further prolonging the hydrothermal time had insignificant effect on the crystal phase composition, crystallinity, and morphologies of the prepared nanocubic pyrite crystals. In contrast, when a mixture of Na2S and S powder was used to replace the thiourea as the sulfur source, tetragonal, orthorhombic, cubic, and irregular pyrite crystal particles with sizes of 100 nm–1 μm were found to co-exist in the prepared samples. These results demonstrate the critical influence of sulfur source on pyrite morphology. Furthermore, our hydrothermal process, using a combination of greigite and thiourea, is proved to be effective in preparing nanocubic pyrite crystals. Our findings can also provide new insight into the formation environments and pathways of nanocubic pyrite under hydrothermal conditions.
Sorption of nanoparticles on mineral surfaces has been well recognized for its environmental implication. For certain gold ore deposits, sorption of gold nanoparticles (AuNPs) on pyrite may constitute a critical step in the metallogenesis process, yet it has not been adequately investigated. In this work, we synthesized negatively charged, positively charged AuNPs and pyrite respectively, and experimentally studied sorption of AuNPs on pyrite in an anaerobic environment. The effects of AuNPs charge characteristics, pH, hexadecyl trimethyl ammonium bromide (CTAB) concentration, and ionic strength were evaluated. For the negatively charged AuNPs, almost no sorption was observed owing to the electrostatic repulsion between the AuNPs and pyrite surface (with a measured isoelectric point of 2.0). In contrast, positively charged AuNPs could be significantly adsorbed on pyrite through electrostatic attraction, with the sorption extent decreasing with the increase of pH (2.2–9.1). However, the adsorption of CTAB from the solution was found to increase with the increase of pH. Furthermore, deliberately added CTAB seemed to inhibit the sorption of AuNPs. Our study not only demonstrates that the electrostatic interaction is the dominant mechanism in the sorption of AuNPs on pristine pyrite, but also reveals the important competitive relation between AuNPs and CTAB in the sorption process.
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