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This work applied the radiotracer technique to evaluate the chromium (Cr) sorption by sediments of a mangrove degraded area under reforestation phase. The radiotracer 51 Cr(III) was used to assess the removal kinetics of this metal from tidal water by underlying sediments in two different environments from the mangrove area of the reserve Parque Natural Municipal Barão de Mauá (Rio de Janeiro, SE Brazil). The results indicated a faster Cr(III) removal by sediments from the area with initial mangrove reforestation (t1/2 = 12.1 ± 0.1 h) than estimated for the area with older mangrove reforestation (t1/2 = 18.0 ± 0.2 h). However, this difference was explained by a stronger sediment bioturbation in the area that presented faster Cr removal (the initial mangrove reforestation zone). These results evidence the importance of the influence of biological activity in the capacity of the mangrove sediment to remove Cr(III) from tidal waters.

In southern Europe, climate change is expected to aggravate water scarcity conditions and challenge current water management practices. The present paper evaluates the impacts of climate change in the highly regulated Tagus River basin and assesses various adaptation options, quantifying the effort needed to maintain the ability to sustain current water uses. A water management and allocation model covering surface and groundwater resources is used to evaluate available and renewable water resources for different climate scenarios. Additionally, the Water Exploitation Index Plus (WEI+) and water supply reliability criteria are used to quantify water scarcity and the ability to satisfy water demands, respectively. The results show that climate change will significantly change the stream flow regime and reduce water availability in the Tagus River basin, but the existing reservoir infrastructure will alleviate some of these impacts, especially in the dry half-year. Until the end of the century, water scarcity levels, measured by annual WEI+, are expected to increase in the Tagus River basin from 0.46 to 0.52 or 0.62, respectively under two Representative Concentration Pathways (RCP 4.5 or RCP 8.5). The benefits of streamflow regulation vary with the hydrological regimen, the current degree of water use and the role of groundwater resources to meet demand. The benefits of streamflow regulation are also dependent on the environmental flow requirements that will be adopted in the future. A reduction of water consumption for irrigation by 25% to 40% will significantly improve the Tagus River system performance and maintain the current scarcity situation in the future, under the expected scenarios of climate change.

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